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Electronic devices, lithium-ion secondary batteries, and positive electrode active materials for lithium-ion secondary batteries

机译:电子设备,锂离子二次电池以及锂离子二次电池用正极活性物质

摘要

Provided is a positive electrode active material for a lithium ion secondary battery having favorable cycle characteristics and high capacity. A covering layer containing aluminum and a covering layer containing magnesium are provided on a superficial portion of the positive electrode active material. The covering layer containing magnesium exists in a region closer to a particle surface than the covering layer containing aluminum is. The covering layer containing aluminum can be formed by a sol-gel method using an aluminum alkoxide. The covering layer containing magnesium can be formed as follows: magnesium and fluorine are mixed as a starting material and then subjected to heating after the sol-gel step, so that magnesium is segregated.
机译:本发明提供一种循环特性良好且容量高的锂离子二次电池用正极活性物质。在正极活性物质的表面部分设置有包含铝的覆盖层和包含镁的覆盖层。包含镁的覆盖层存在于比包含铝的覆盖层更靠近粒子表面的区域中。包含铝的覆盖层可以使用铝醇盐通过溶胶-凝胶法形成。可以如下形成含镁的覆盖层:将镁和氟作为原料混合,然后在溶胶-凝胶步骤之后进行加热,以使镁偏析。

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