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Method of epoxidation of propene

机译:丙烯环氧化的方法

摘要

Using propene in excess relative to hydrogen peroxide, continuously reacting the propene feed with hydrogen peroxide in the presence of an epoxidation catalyst in the reaction step to provide a liquid reaction mixture comprising unreacted propene (epoxidation reaction An additional safety measure caused by the presence of oxygen during the work-up of the liquid reaction mixture of is avoided by providing an oxygen depleted stripped liquid reaction mixture and strip gas stream by stripping the liquid reaction mixture from step a) with an inert gas. Selecting an amount of inert gas to provide an oxygen concentration in the strip gas stream in the range of 0.1 to 10% by weight, separating the unreacted propene from the strip gas stream and recycling it to the reaction step, And propene oxide from the stripped liquid reaction mixture. Epoxidation of propene, comprising the steps of: Li.
机译:使用相对于过氧化氢过量的丙烯,在反应步骤中在环氧化催化剂的存在下使丙烯进料与过氧化氢连续反应,以提供包含未反应的丙烯的液体反应混合物(环氧化反应由于氧气的存在而引起的附加安全措施)通过提供贫氧的汽提的液体反应混合物和通过用惰性气体汽提来自步骤a)的液体反应混合物来汽提气流来避免在反应的液体反应混合物的后处理过程中。选择惰性气体的量以提供在汽提气流中的氧气浓度为0.1至10重量%,从汽提气流中分离出未反应的丙烯并将其再循环至反应步骤,以及从汽提气中回收环氧丙烷液体反应混合物。丙烯的环氧化,包括以下步骤:Li。

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