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- - PREPARATION OF TRI-ALKYL GALLIUM OR TRI-ALKYL INDIUM COMPOUNDS

机译:--三烷基镓或三烷基铟化合物的制备

摘要

Trialkyl metal compounds, such as trialkyl gallium and indium compounds, are typically monovalent metals such as Li, Na, K or Cs at temperatures from 75 to 160 ° C, R is an alkyl group and X is a halide And n is a number from 1 to 3 in a metal trihalide such as GaCl 3 or InCl 3 and a monovalent metal in an ionic liquid such as a molten salt of the formula M [AIR n X (4-n) ] It is prepared with high yield and high purity by adding a trialkyl aluminum compound to a mixture prepared by adding a halide salt.
机译:三烷基金属化合物(例如三烷基镓和铟化合物)通常是单价金属,例如Li,Na,K或Cs,温度范围为75至160°C,R为烷基,X为卤化物,n为1-3在金属三卤化物(如GaCl 3 或InCl 3 )中和一价金属在离子液体(如式M [AIR n X (4-n)]通过将三烷基铝化合物添加到通过添加卤化物盐制备的混合物中,可以高收率和高纯度地制备。

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