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Effects of steam pretreatment and co-production with ethanol on the energy efficiency and process economics of combined biogas, heat and electricity production from industrial hemp

机译:蒸汽预处理和乙醇联产对工业大麻沼气,热电联产的能效和工艺经济性的影响

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摘要

Background: The study presented here has used the commercial flow sheeting program Aspen Plus (TM) to evaluate techno-economic aspects of large-scale hemp-based processes for producing transportation fuels. The co-production of biogas, district heat and power from chopped and steam-pretreated hemp, and the co-production of ethanol, biogas, heat and power from steam-pretreated hemp were analysed. The analyses include assessments of heat demand, energy efficiency and process economics in terms of annual cash flows and minimum biogas and ethanol selling prices (MBSP and MESP). Results: Producing biogas, heat and power from chopped hemp has the highest overall energy efficiency, 84% of the theoretical maximum (based on lower heating values), providing that the maximum capacity of district heat is delivered. The combined production of ethanol, biogas, heat and power has the highest energy efficiency (49%) if district heat is not produced. Neither the inclusion of steam pretreatment nor co-production with ethanol has a large impact on the MBSP. Ethanol is more expensive to produce than biogas is, but this is compensated for by its higher market price. None of the scenarios examined are economically viable, since the MBSP (EUR 103-128 per MWh) is higher than the market price of biogas (EUR 67 per MWh). The largest contribution to the cost is the cost of feedstock. Decreasing the retention time in the biogas process for low solids streams by partly replacing continuous stirred tank reactors by high-rate bioreactors decreases the MBSP. Also, recycling part of the liquid from the effluent from anaerobic digestion decreases the MBSP. The production and prices of methane and ethanol influence the process economics more than the production and prices of electricity and district heat. Conclusions: To reduce the production cost of ethanol and biogas from biomass, the use of feedstocks that are cheaper than hemp, give higher output of ethanol and biogas, or combined production with higher value products are primarily suggested. Further, practical investigations on increased substrate concentration in biogas and ethanol production, recycling of the liquid in anaerobic digestion and separation of low solids flows into solid and a liquid fraction for improved reactor applications deserves further attention.
机译:背景:此处提出的研究已使用商业流程表程序Aspen Plus(TM)来评估大规模的基于大麻的生产运输燃料的工艺的技术经济方面。分析了切碎的和蒸汽预处理的大麻的沼气联合生产,区域热量和功率,以及蒸汽预处理的大麻的联合生产乙醇,沼气,热量和功率。分析包括根据年度现金流量以及最低沼气和乙醇销售价格(MBSP和MESP)评估热需求,能源效率和过程经济性。结果:从切碎的大麻中生产沼气,热量和电力具有最高的总能源效率,是理论最大值的84%(基于较低的热值),前提是要提供最大的区域供热能力。如果不产生区域热量,则乙醇,沼气,热能和动力的联合生产具有最高的能源效率(49%)。既不包括蒸汽预处理也不包括与乙醇的联产对MBSP都没有很大的影响。乙醇生产成本高于沼气,但这可以通过其较高的市场价格来弥补。由于MBSP(每兆瓦时103-128欧元)高于沼气的市场价格(每兆瓦时67欧元),因此没有一种方案在经济上可行。成本的最大贡献是原料成本。通过用高速率生物反应器部分替代连续搅拌釜反应器,减少低固体流沼气工艺中的保留时间,从而降低了MBSP。同样,厌氧消化废水中的部分液体再循环会降低MBSP。甲烷和乙醇的生产和价格对过程经济的影响大于电力和区域供热的生产和价格。结论:为降低生物质生产乙醇和沼气的成本,主要建议使用比麻便宜的原料,乙醇和沼气的产量更高的原料,或与更高价值的产品联合生产。此外,有关沼气和乙醇生产中底物浓度增加,厌氧消化中液体的再循环以及低固体分离成固体和液体馏分以改善反应器应用的实践研究值得进一步关注。

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