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The temperature dependence of Laminar burning velocities of methanol-syngas-air flames

机译:甲醇 - 合成气 - 空气火焰层流燃烧速度的温度依赖性

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摘要

Using the simplest alcohol – methanol – as a fuel for spark ignition (SI) engines, enables an increase of thermal efficiency compared to gasoline. Additionally, with the enrichment of hydrogen rich gas from methanol reforming (syngas) using exhaust heat, the efficiency can be further improved. The complexity of optimizing such an arrangement asks for numerical support. However, there is no research that publishes the effect of unburned mixture temperature and equivalence ratio on the laminar burning velocity of methanol-syngas blends, which is needed for developing an engine cycle code to simulate methanol fueled SI engines with syngas addition from exhaust gas fuel reforming. The influence of temperature on the laminar burning velocity of methanol-syngas blends is investigated in this study using CHEM1D. The simulation shows that the flame speed increases dramatically with the enrichment of syngas, especially at lean and rich conditions. The effect of syngas ratio on the improvement of burning velocity is less important at higher temperatures, and there is almost no influence at stoichiometry. Some well-known mixing rules are then examined. In general, the Hirasawa mixing rule shows the best fit with the numerical data. For blends with high syngas content, the Le Chatelier’s mixing rule is recommended. The temperature power exponent α is calculated and compared to other correlations. It shows that the published correlations are unable to predict the influence of temperature on laminar burning velocity accurately enough for the combustion of methanol, syngas and their blends in air.
机译:与汽油相比,使用最简单的醇(甲醇)作为火花点火(SI)发动机的燃料可以提高热效率。另外,通过利用废热从甲醇重整(合成气)中富集富氢气体,可以进一步提高效率。优化这种安排的复杂性需要数字支持。但是,尚无研究发表未燃混合物温度和当量比对甲醇-合成气混合物层流燃烧速度的影响,这对于开发发动机循环代码来模拟从废气燃料中添加合成气的甲醇燃料SI发动机是需要的。重整。在这项研究中,使用CHEM1D研究了温度对甲醇-合成气混合物层流燃烧速度的影响。仿真表明,随着合成气的富集,火焰速度急剧增加,特别是在稀薄和浓稠条件下。合成气比例对提高燃烧速度的影响在较高温度下不太重要,并且对化学计量几乎没有影响。然后检查一些众所周知的混合规则。通常,平泽混合法则显示出与数值数据的最佳拟合。对于合成气含量较高的混合物,建议使用Le Chatelier的混合规则。计算温度功率指数α并将其与其他相关性进行比较。结果表明,已发表的相关性无法准确预测温度对层流燃烧速度的影响,不足以使甲醇,合成气及其混合物在空气中燃烧。

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