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Characterization of glass fibre reinforced polyamide/acrylonitrile butadiene-styrene composite for automotive application

机译:用于汽车的玻璃纤维增​​强聚酰胺/丙烯腈丁二烯-苯乙烯复合材料的表征

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摘要

Polyamide-6 (PA6), acrylonitrile-butadiene-styrene (ABS) and their blends are an important class of engineering thermoplastics that are widely used especially for automotive industries. Many efforts have been taken to improve the properties of both pure components and the blends. It was for this reason that the dynamic mechanical and rheological properties of PA6/ABS blend systems compatibilised by acrylonitrilebutadiene- styrene–maleic anhydride (ABS-g-MAH) was studied. The compatibiliser level was kept up to 5wt. % in the blends. Short glass fibre (SGF) was used to improve the stiffness of the compatibilised blends and the concentration was varied from 10 to 30 wt. %. Therefore, the reason behind of blending the PA6/ABS blends with short glass fibre was to balance the toughness and stiffness. The blends and corresponding composites were compounded using a co-counter twin srew extruder. Tensile, flexural and impact properties were determined using the injection moulded test samples according to ASTM standards. Dynamic mechanical analyses (DMA) were carried out to investigate the dynamic mechanical behaviour of the blends and composites. Rheological properties were carried out using dynamic and capillary rheometer. In general, the mechanical strength either dynamic (refer to DMA) or static conditions were improved by incorporation of compatibiliser to the PA6/ABS blends. The incorporation of SGF into the PA6/ABS blends enhanced the mechanical strength however, reduced the toughness of the composites. The rheological measurements confirmed the increased in interaction between the blend components with the incorporation of compatibiliser The compatibiliser has no favourable effect on the mechanical properties of the composites although it has significant effect on the blends of PA6/ABS. ABS-g-MAH increases the melt viscosity of the blends. The SGF increased the rheological properties especially viscosity and flowability of the composites. The optimum ratio compatibiliser and SGF concentration were successfully determined using power law and consistency index analysis. From the analysis the optimum ratio obtained was 1.5 wt. % for 50/50 and 60/40 PA6/ABS blends and 3 wt. % for 70/30 PA6/ABS blends. When the SGF introduced at 20 wt. % concentration, the values of n drastically decreased indicating more pseudoplastic nature for the composites and concluded that, the optimum concentration of SGF was about 20 wt. %.
机译:聚酰胺6(PA6),丙烯腈-丁二烯-苯乙烯(ABS)及其共混物是一类重要的工程热塑性塑料,广泛用于汽车工业。已经进行了许多努力来改善纯组分和共混物的性能。因此,研究了丙烯腈-丁二烯-苯乙烯-马来酸酐(ABS-g-MAH)相容的PA6 / ABS共混体系的动态力学和流变性能。相容剂水平保持在5wt%以下。混合中的百分比。短玻璃纤维(SGF)用于改善相容混合物的刚度,其浓度在10至30 wt%之间变化。 %。因此,将PA6 / ABS共混物与短玻璃纤维共混的原因是要平衡韧性和刚度。使用同柜台双螺杆挤出机将共混物和相应的复合材料复合。使用根据ASTM标准的注塑测试样品测定拉伸,挠曲和冲击性能。进行了动态力学分析(DMA)以研究共混物和复合材料的动态力学行为。流变性质使用动态和毛细管流变仪进行。通常,通过将相容剂掺入PA6 / ABS共混物中可改善动态(指DMA)或静态条件下的机械强度。将SGF掺入PA6 / ABS共混物中可提高机械强度,但会降低复合材料的韧性。流变学测量证实掺入相容剂可增加共混物组分之间的相互作用。增容剂虽然对PA6 / ABS共混物有显着影响,但对复合材料的机械性能没有有利影响。 ABS-g-MAH可提高混合物的熔融粘度。 SGF提高了复合材料的流变性能,特别是粘度和流动性。使用幂律和一致性指数分析成功确定了最佳比例相容剂和SGF浓度。根据分析,获得的最佳比例为1.5重量%。 50/50和60/40 PA6 / ABS共混物的重量百分比为3%。 70/30 PA6 / ABS共混物的%。当SGF以20wt。%引入时。 %浓度时,n值急剧降低,表明复合材料具有更多的假塑性,并得出结论,SGF的最佳浓度为约20wt。%。 %。

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