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Investigation of using sulfur-containing gases in low-temperature fuel cell at sulfuric acid production site

机译:硫酸生产现场在低温燃料电池中使用含硫气体的研究

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摘要

The possibility and effectiveness of using sulfur dioxide and hydrogen sulfide as the fuel in lowtemperaturefuel cells at the sulfuric acid production site has been investigated. A fuel cell has been designedand constructed using palladium as a catalyst, which enables conversion of the energy of oxidation of sulfurdioxide and hydrogen sulfide to the electric energy. The experimental data showed that the use of hydrogensulfide and sulfur dioxide as a fuel allows achieving the power of 1.0 and 0.5 mW, respectively. Thecomparative studies with the use of hydrogen in the same fuel cell resulted in the power of about 2.0 mW,i.e. the use of hydrogen sulfide delivers a performance comparable with that of the hydrogen. The processesof oxidizing of the sulfur containing gases are used in our company in production of sulfuric acid. Oxidationof these gases conducted using the conventional technological processes. The use of these processes toproduce energy as a byproduct could be an attractive way to reduce the energy consumption of the wholeprocess. Considering the relatively high power obtained in this work for the sulfur containing gases fed fuelcells, the substitution of conventional oxidation of sulfur containing gases in this technological chain by thefuel cell oxidation, and by-producing the electric energy, could be very profitable for the energy efficiencyenhancement of the main production process. In the future work, the design and development of fuel cellcatalysts and membranes to enhance the performances of sulfur containing fuel cells will be significant.
机译:已经研究了在硫酸生产现场在低温燃料电池中使用二氧化硫和硫化氢作为燃料的可能性和有效性。已经设计和构造了使用钯作为催化剂的燃料电池,其使得能够将二氧化硫和硫化氢的氧化能转换成电能。实验数据表明,使用硫化氢和二氧化硫作为燃料可分别实现1.0 mW和0.5 mW的功率。在同一燃料电池中使用氢的比较研究得出的功率约为2.0 mW,即使用硫化氢可提供与氢相当的性能。我们公司在硫酸生产中使用了氧化含硫气体的方法。这些气体的氧化使用常规工艺进行。这些过程的使用产生能量作为副产物可能是减少整个过程能耗的一种有吸引力的方法。考虑到在这项工作中获得的供入燃料电池的含硫气体的功率相对较高,因此在该技术链中用燃料电池的氧化取代常规的含硫气体氧化,并通过产生电能,对于该能源可能非常有利主要生产过程的效率提高。在未来的工作中,提高含硫燃料电池性能的燃料电池催化剂和膜的设计和开发将具有重要意义。

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