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Recycling of automotive waste materials for manufacturing lightweight and porous clay-based materials

机译:回收汽车废料以生产轻质和多孔粘土基材料

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摘要

50 million tonnes of automotive waste is generated each year around the globe. Due to development of technology and increase of automobiles, dumping and management of end of life vehicles have become significant environmental and health issues. The use of lightweight plastics and glasses in automotive industry is increasing rapidly due to consumer demand for fuel efficient vehicles. 12-15% of plastics are used in vehicles, and plastic percentage will increase significantly in near future. Average weight of car is around 1500 kg and contains 180-225 kg of plastic materials. Recycling automotive waste is very tedious and difficult due to its heterogeneous composition and nature. Hence, automotive waste is disposed in landfills and has become a major threat to environment. This work investigates the utilization of automotive shredded residue (ASR) and automotive waste glasses as resources to produce lightweight clay based materials for different applications. For this study, clay was supplied by Brickworks Limited, Sydney and waste materials such as ASR and automotive glasses were collected from OneSteel Recycling, Newcastle, Australia. The obtained materials were characterized by carbon and sulphur analyzer, X-ray fluorescence (XRF) spectroscopy, Inductive coupled plasma (ICP) spectroscopy techniques to determine the elemental compositions. The plastics in ASR were analysed by using FT-IR method. Thermal stability of materials was also studied by using thermal analyzer. The results signify that ASR contains majorly polymers, and minor quantities of wood and metals. TGA result of ASR indicates that major weight loss occurs around 380-430℃ with 4-5% solid residue. From the results, it is clearly understood that ASR produces various gases during thermal decomposition and hence can be utilized in manufacturing lightweight clay based materials. The lightweight clay materials were produced by using (a) 1 wt.% ASR and (b) 2 wt.% ASR with clay. The ratios of mixtures were prepared by using water to form pellets. The ASR/clay pellets were dried in hot air oven to remove water content. Sintering process was performed at industrial working temperature 1200℃ for 20 minutes in horizontal tubular furnace. The sintered pellets were subjected for characterization of basic physical properties such as density and porosity which were conducted according to ASTM standards (Archimedes method). Analytical techniques such as SEM-EDS, XRD and compression tests were also used to analyze sintered pellets. The results suggest that the addition of ASR to clay material increases both volume and porosity, and decreases density compared to 100% clay respectively. The compression test results indicate the slight decrease in the mechanical strength of sintered pellets. Hence, waste glass and alumina were used as additives along with ASR in clay to study the effect on mechanical properties. The addition of glass to ASR/clay mixture did not show any significant changes in mechanical properties, whereas alumina addition to ASR/clay mixture showed increase in mechanical property. Alumina acts as a reinforcing material in ASR/clay composites, which helps to attain the mechanical strength as similar to 100% clay. Recycling of ASR by using alumina in manufacturing lightweight clay materials shows promising results in terms of volume increase, porosity increase and also decrease in density without much change in mechanical properties. The obtained superior lightweight and porous clay products by using only ASR can be used in thermal insulation materials and also as substrates in soilless cultivation. The lightweight and high mechanical strength clay aggregates obtained by using ASR and alumina can be used in concrete slab mixes and as pellet pavements. This innovative approach offers a novel solution for increasing recycling rate of automotive waste and also could be a new opportunity for manufacturing industries to incorporate waste materials as resources.
机译:全球每年产生5000万吨汽车废物。由于技术的发展和汽车的增加,报废汽车的弃置和管理已成为重要的环境和健康问题。由于消费者对节油型汽车的需求,汽车工业中轻质塑料和玻璃的使用正在迅速增加。 12-15%的塑料用于汽车,塑料的百分比将在不久的将来显着增加。汽车的平均重量约为1500公斤,其中包含180-225公斤的塑料。由于汽车废弃物的成分和性质各不相同,因此其回收非常繁琐且困难。因此,汽车废料被丢弃在垃圾填埋场中,已经成为对环境的主要威胁。这项工作研究了利用汽车碎渣(ASR)和汽车废玻璃作为生产轻质粘土基材料用于不同应用的资源。在这项研究中,粘土是由悉尼的Brickworks Limited提供的,而废料如ASR和汽车玻璃则是从澳大利亚纽卡斯尔的OneSteel Recycling收集的。通过碳和硫分析仪,X射线荧光(XRF)光谱,感应耦合等离子体(ICP)光谱技术对所得材料进行表征,以确定元素组成。采用FT-IR法分析了ASR中的塑料。还使用热分析仪研究了材料的热稳定性。结果表明,ASR主要包含聚合物,以及少量的木材和金属。 ASR的TGA结果表明,主要的重量损失发生在380-430℃左右,固体残渣为4-5%。从结果可以清楚地了解到,ASR在热分解过程中会产生各种气体,因此可用于制造轻质粘土基材料。通过使用(a)1重量%的ASR和(b)2重量%的ASR与粘土来生产轻质粘土材料。通过用水形成颗粒来制备混合物的比例。将ASR /粘土粒料在热风炉中干燥以除去水分。在卧式管式炉中于工业工作温度1200℃进行20分钟烧结。对烧结的粒料进行表征,以表征根据ASTM标准(Archimedes方法)进行的基本物理性质,例如密度和孔隙率。 SEM-EDS,XRD和压缩测试等分析技术也被用于分析烧结球团。结果表明,与100%粘土相比,向粘土材料中添加ASR会增加体积和孔隙率,并降低密度。压缩试验结果表明,烧结颗粒的机械强度略有降低。因此,废玻璃和氧化铝与粘土中的ASR一起用作添加剂,以研究其对机械性能的影响。将玻璃添加到ASR /粘土混合物中没有显示出机械性能的任何显着变化,而将氧化铝添加到ASR /粘土混合物中显示出机械性能的增加。氧化铝在ASR /粘土复合材料中充当增强材料,与100%粘土相似,有助于获得机械强度。通过在生产轻质粘土材料中使用氧化铝回收ASR,在体积增加,孔隙率增加以及密度降低方面显示出令人鼓舞的结果,而机械性能没有太大变化。仅通过使用ASR获得的优异的轻质和多孔粘土产品既可以用于绝热材料,也可以用作无土栽培的基质。通过使用ASR和氧化铝获得的轻质和高机械强度粘土骨料可用于混凝土板混合料和颗粒路面。这种创新方法为提高汽车废料的回收率提供了一种新颖的解决方案,也可能成为制造业将废料纳入资源的新机会。

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