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On hearth phenomena and hot metal carbon content in blast furnace

机译:高炉炉缸现象与铁水碳含量的关系

摘要

The objective of this work was to investigate the hearth operation and the factors influencing the total quality of hot metal, especially its carbon and sulphur contents. Regarding the hot metal quality there are many sources of disturbances starting from raw materials, continuing through the blast furnace process and ending the hot metal casting.The carbon content of hot metal is an important part of the total quality of hot metal. Nearly 80 % of the total reaction energy in the BOF process comes from the oxidation of carbon in hot metal. Therefore, a high and stable carbon content of hot metal is most beneficial. Sulphur in hot metal is known to retard the carbonisation of hot metal. The sulphur content in hot metal is controlled by the sulphur load in the coke and other fuels as well as the slag basicity and low level of unreduced iron oxides.Both carbonisation and desulphurisation are strongly dependent on the hearth operation. To secure a proper hearth operation the hearth coke, the deadman should neither be clogged nor get inactive. Good hearth operation prolongs the campaign life of the hearth lining improving thus the total economy.In this work the factors influencing the hot metal carbon content have been investigated. The carbonisation of solid iron starts in the shaft by CO gas and also by coke carbon when the metal melts down. Hot metal does not get saturated with carbon. The difference between the saturation and actual carbon contents was observed to be around 0.7 % in average and it increases with increasing sulphur content. The carbon content of hot metal can be maintained on a high level by keeping the sulphur content of hot metal below 0.05 % which can be attained with a sufficient slag basicity, e.g. CaO / SiO = 1.2.A progressive vicious circle in blast furnace operation was observed. Problems may start with some disturbance in the hearth operation gradually resulting in low permeability or total clogging of the deadman. The raceways become shorter which leads to a hanging cohesive zone. A hanging cohesive zone transfers insufficiently reduced iron oxides into the slag. Desulphurisation of hot metal weakens due to a higher FeO content in the slag. A high sulphur content in hot metal promotes the precipitation of calcium sulphide. Calcium sulphide together with other compounds with high melting point may clog the hearth further. There are several factors which strengthen vicious circle like a low heat level, an overfilled hearth, too acid slag etc.Different factors influencing the hearth phenomena and start up of the vicious circle including CaS precipitation were observed and analysed in this work. Early warning symptoms of a clogged hearth and methods to identify an inactive deadman were collected. Measures to cure an inactive deadman were developed and practised as well.
机译:这项工作的目的是研究炉床的运行情况以及影响铁水总质量的因素,尤其是其碳和硫含量。关于铁水质量,有许多干扰源,从原材料开始,一直到高炉过程一直到铁水浇铸结束。铁水的碳含量是铁水总质量的重要组成部分。转炉过程中总反应能量的近80%来自铁水中碳的氧化。因此,高而稳定的铁水碳含量是最有益的。已知铁水中的硫会阻碍铁水中的碳化。铁水中的硫含量受焦炭和其他燃料中的硫负荷以及炉渣碱度和未还原的氧化铁含量低的影响。碳化和脱硫都强烈依赖于炉床操作。为了确保炉膛焦炭正常工作,死者既不应被阻塞,也不应处于活动状态。良好的炉膛运行可延长炉膛衬里的运动寿命,从而改善整体经济性。在这项工作中,研究了影响铁水碳含量的因素。固态铁的碳化是通过CO气体在竖井中开始的,当金属熔化时也通过焦炭开始的。铁水不会被碳饱和。饱和碳含量与实际碳含量之间的差异平均约为0.7%,并且随着硫含量的增加而增加。通过将铁水的硫含量保持在0.05%以下,可以将铁水的碳含量保持在较高水平,这可以用足够的矿渣碱度实现,例如CaO / SiO = 1.2。在高炉操作中观察到一个渐进的恶性循环。问题可能始于炉床操作中的某些干扰,逐渐导致渗透率低或死亡者完全堵塞。滚道变短,导致悬挂的粘聚区。悬挂的粘性区将还原不足的氧化铁转移到炉渣中。铁水的脱硫由于炉渣中较高的FeO含量而减弱。铁水中的高硫含量会促进硫化钙的沉淀。硫化钙与其他高熔点化合物可能会进一步阻塞炉膛。较低的热量水平,炉膛过满,炉渣太酸等因素会加剧恶性循环。在这项工作中,观察和分析了影响炉膛现象和恶性循环启动的各种因素,包括CaS沉淀。收集了炉膛堵塞的预警症状和识别无活动死者的方法。还制定并实施了治疗无效的死刑者的措施。

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  • 作者

    Raipala Kalevi;

  • 作者单位
  • 年度 2003
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  • 原文格式 PDF
  • 正文语种 en
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