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Magneto-Optic Polymers and Devices

机译:磁光聚合物和器件

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摘要

For several decades, the field of magneto-optics (MO) has demonstrated applications that have impact on every day applications such as in optical data storage, magnetic field sensing, crucial for magnetoencephalography and magnetocardiography; and compact and efficient optical isolators, among others. In the past, many of these applications and the devices designed for them have heavily relied on inorganic materials. Organic materials with a high MO response represent an interesting alternative to the inorganic equivalent by not only being a more cost efficient solution, but also by allowing the user to modify a number of variables to control and optimize the MO performance depending on the application and level of performance desired. In this dissertation I discuss the MO properties of novel organic materials, starting with polythiophene, which has been of interest due to the strong relationship between its high MO performance and its lamellar structure and regioregularity. I will also be discussing another material system that provides several degrees of MO tunability: magnetite based nanocomposites. A unique and novel synthetic approach described in this dissertation yields both highly transparent and MO responsive polymer films. I will be describing a systematic approach that indicates a strong influence of the size of the nanoparticle as well as the nanoparticle concentration in the MO performance of the bulk polymer, while maintaining high optical quality with minimal scattering and absorption in the visible and near infrared. Finally, I will be discussing the implementation of both a magnetite nanocomposite and a cobalt ferrite based nanocomposite in a free space magnetic field system and demonstrate the proof-of-principle operation of a sensing system.
机译:几十年来,磁光(MO)领域已经证明了对日常应用有影响的应用,例如在光学数据存储,磁场感应,对脑磁图和心磁图至关重要的应用中;以及紧凑高效的光学隔离器等。过去,许多此类应用程序和为其设计的设备都严重依赖无机材料。具有高MO响应的有机材料不仅是一种更具成本效益的解决方案,而且还允许用户根据应用和级别修改许多变量来控制和优化MO性能,从而代表了一种等效的替代无机物的方法。所需的性能。在本文中,我从聚噻吩开始讨论了新型有机材料的MO性质,由于其高MO性能与其层状结构和区域规则性之间的密切关系,人们一直对此感兴趣。我还将讨论另一种可提供多种MO可调性的材料系统:基于磁铁矿的纳米复合材料。本文所描述的独特新颖的合成方法可产生高度透明和MO响应的聚合物薄膜。我将描述一种系统的方法,该方法表明纳米颗粒的大小以及纳米颗粒浓度对本体聚合物的MO性能有很大影响,同时保持高光学质量,同时在可见光和近红外光中具有最小的散射和吸收。最后,我将讨论在自由空间磁场系统中磁铁矿纳米复合材料和钴铁氧体纳米复合材料的实现,并演示传感系统的原理验证。

著录项

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    Lopez Santiago Alejandra;

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  • 年度 2014
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