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Deacidification of high acidic rubber seed oil byudreesterification with glycerol

机译:高酸性橡胶籽油的脱酸用甘油再酯化

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摘要

Some studies have shown that rubber seed oil (RSO) from the seed of rubber tree (hevea brasiliensis)has potential technical applications. However, the high free fatty acid (FFA) associated with the oil may be a limiting factor in its applications. In this study, crude rubber seed oil (RSO) containing 37.69% FFA was deacidified using 4.3-5.6% of glycerol. The reactions were carried out at a pressure of 20mmHg in the presence of zinc dust and zinc chloride catalysts added separately at high temperature (150 –ud2500C). The progress of the reaction was monitored by determining the FFA at various time intervals.The FFA content in the RSO was reduced to 1.5% in six hours when 4.3% glycerol was used with zinc dust at a temperature of 2000C while the triglycerides content of the oil increased from 40.32% in the crude oil to 80.62% in the deacidified RSO. The study showed that this process is effective in theuddeacidification of RSO without loss of neutral glycerides as in alkali neutralization.
机译:一些研究表明,橡胶树种子(巴西橡胶树)的橡胶种子油(RSO)具有潜在的技术应用。但是,与油相关的高游离脂肪酸(FFA)可能是其应用中的限制因素。在这项研究中,使用4.3-5.6%的甘油将含有37.69%FFA的粗橡胶籽油(RSO)脱酸。反应是在20mmHg的压力下,在高温(150 – ud2500C)下分别添加锌粉和氯化锌催化剂的条件下进行的。通过在不同时间间隔测定FFA来监测反应进程。当在2000°C的温度下将4.3%甘油与锌粉一起使用时,RSO中的FFA含量在6小时内降至1.5%。油从原油中的40.32%增加到脱酸RSO中的80.62%。研究表明,该方法在RSO的 uddeacidization中有效,而不会像碱中和那样损失中性甘油酯。

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