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Feasibility of ASH DEC‐ process in treating sewage sludge and manure ash in Finland

机译:ASH DEC法在芬兰处理污水污泥和肥料灰的可行性

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摘要

In Finland the thermal treatment of sewage sludge has been moderate in 21th century. Thereason has been the high moisture content of sludge. During 2005-2008, 97-99% of sewagesludge was utilized in landscaping and agriculture. However agricultural use has been during2005-2007 less than 3 %. The aim of national waste management plan is that by 2016 100%of sludge is used either as soil amendment or energy. The most popular utilization methodfor manure is spreading it on arable land. The dry manures such as poultry manure and horsemanure could also be used in incineration. The ashes could be used as fertilizers and while itis not suitable as a starter fertilizer, it is suitable in maintaining P levels in the soil. One ofthe main drivers for more efficient nutrient management is the eutrophication in lakes andthe Baltic See.ASH DEC process can be used in concentrating phosphorus rich ashes while separating theheavy metals that could be included. ASH DEC process uses thermochemical treatment toproduce renewable phosphate for fertilizer production. The process includes mixing of ashesand chlorine donors and subsequent treatment in rotary kiln for 20 min in temperature of 900– 1 050 oC. The heavy metals evaporate and P-rich product is obtained. The toxic substancesare retained in air pollution control system in form of mixed metal hydroxides.The aim of conducting this study is to estimate the potential of ASH DEC process in treatingphosphorus rich ashes in Finland. The masses considered in are sewage sludge, dry manurefrom horses, and poultry and liquid pig manure.To date the usual treatment method for sewage sludge in Finland is composting or anaerobicdigestion. Part of the amount of produced sewage sludge (800 kt/a fresh mass and 160 kt/aTS) could also be incinerated and the residual ashes used in ASH DEC process. Incineratingonly manure can be economically difficult to manage because the incineration of manure isin Finland considered as waste incineration. Getting a permit for waste incineration isdifficult and also small scale waste incineration is too expensive. The manure could act as anadditional feedstock in counties with high density of animal husbandry where the land areamight not be enough for spreading of manure. Now when the manure acts as asupplementary feedstock beside sludge, the ash can’t be used directly as fertilizer. Then itcould be used in ASH DEC process. The perquisite is that the manure producers could payfor the incineration, which might prove problematic.
机译:在芬兰,对污水污泥的热处理在21世纪一直很温和。因此,污泥的水分含量很高。在2005-2008年期间,有97-99%的污水污泥被用于园林绿化和农业。但是,2005-2007年间农业使用率不到3%。国家废物管理计划的目标是到2016年将100%的污泥用作土壤改良剂或能源。肥料最普遍的利用方法是在耕地上传播。干粪如家禽粪便和马粪也可用于焚烧。骨灰可以用作肥料,虽然不适合用作起始肥料,但它适合保持土壤中的磷水平。湖泊和波罗的海的富营养化是提高营养素管理效率的主要驱动力之一。ASHDEC工艺可用于浓缩富磷的灰烬,同时分离出可能包含的重金属。 ASH DEC工艺使用热化学处理来生产可再生的磷酸盐,用于肥料生产。该过程包括将灰分和氯供体混合,然后在900–1050℃的温度下在回转窑中处理20分钟。重金属蒸发并获得富磷产物。有毒物质以混合金属氢氧化物的形式保留在空气污染控制系统中。进行本研究的目的是评估ASH DEC工艺在处理富磷灰分中的潜力。考虑的污物是污水污泥,马干粪便以及家禽和液态猪粪。迄今为止,芬兰污水污泥的常用处理方法是堆肥或厌氧消化。产生的一部分污泥(800 kt / a的新鲜污泥和160 kt / aTS)的一部分也可以被焚化,剩余的灰烬用于ASH DEC工艺。仅焚化粪便在经济上难以管理,因为在芬兰,焚化粪便被视为废物焚化。很难获得废物焚化许可证,而且小规模的废物焚化也太昂贵了。在畜牧密度高的县,这些土地可​​能不足以传播肥料,粪便可以作为补充原料。现在,当肥料用作污泥的补充原料时,灰烬不能直接用作肥料。然后可以在ASH DEC过程中使用。合理的是,粪便生产者可以为焚化买单,这可能会带来问题。

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