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Pitch detackification with natural and modified talcs

机译:用天然和改性滑石进行沥青去粘

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摘要

Pitch deposition in the pulp or in different parts of the manufacturing system can lead to a decrease in the quality of the final paper produced and to manufacturing efficiency problems. Tackiness is the property of pitch which related to the deposit formation. One of the methods to control pitch deposition in the pulp and paper industry is the use of the talc. The talc acts primarily by a detackification mechanism and hence must be part of the deposit to control further deposition. The effectiveness of talc as control agent depends on its structural and surface characteristics, e.g. specific surface, surface energy, surface charge and ratio lypophilic/hydrophilic surface, being these related to its mineral composition and the thermal and surface treatments it has undergone. Five commercial talcs, corresponding to two groups of different mineralogical compositions, have been tested to determine their detackification capacity using the deposition tester developed by the Complutense University of Madrid. In this method, the quantification of the deposits is carried out by an image analysis (IA) of stainless steel collectors on which the deposit has formed. After IA a qualitative analysis to determine the deposit organic fraction is carried out by gas chromatography (CG) after deposit extraction.udThe detackification capacity is expressed as the reduction of the deposits formed on the collectors when the different talcs at several concentrations are added to the pulp suspensions. The results show that pitch detackiness by talc addition is related to talc concentration and surface properties of mineral, as for example chlorite proportion, surface area and surface treatment and to the adsorption capacity of pitch on talcs. The general conclusions are that the talc having the highest quantity of mineral talc presents the best detackification capability and that all talcs studied have an appreciable detackification reduction at low proportion of addition.
机译:在纸浆中或在制造系统的不同部分中的沥青沉积会导致所生产的最终纸张的质量下降以及制造效率问题。粘性是沥青的性质,与沉积物的形成有关。在制浆和造纸工业中控制沥青沉积的方法之一是使用滑石。滑石主要通过去粘机制起作用,因此必须是沉积物的一部分以控制进一步的沉积。滑石粉作为控制剂的有效性取决于其结构和表面特性,例如。比表面积,表面能,表面电荷和亲脂性/亲水性表面的比率,与它们的矿物成分以及所经历的热处理和表面处理有关。使用马德里Complutense大学开发的沉积测试仪测试了五种商业滑石,分别对应两组不同的矿物学组成,以确定其脱粘能力。在这种方法中,沉积物的定量是通过对形成有沉积物的不锈钢收集器的图像分析(IA)进行的。 IA后,对沉积物进行萃取后,通过气相色谱(CG)进行定性分析,以确定沉积物的有机物含量。纸浆悬浮液。结果表明,通过添加滑石粉引起的沥青脱粘性与滑石粉的浓度和矿物的表面性质有关,例如亚氯酸盐的比例,表面积和表面处理,以及沥青在滑石粉上的吸附能力。总的结论是,滑石含量最高的滑石粉具有最好的防粘能力,并且所有研究的滑石在添加比例较低的情况下都有明显的防粘能力。

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