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Untersuchungen zum Betriebsverhalten temperaturregelbarer OFW-Gassensoren

机译:温度可控声表面波气体传感器的工作特性研究

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摘要

Generally Surface Acoustic Wave (SAW) gas sensors are based on piezoelectric crystals like silicon oxide or lithium niobate and are often manufactured with a complicated technology. In order to reach high temperature stability, special crystal cuts are used. These cuts often show a small temperature gradient. Further on, a temperature compensation via mixer circuit is often applied. For the detection of specific components in undefined gas mixtures, the mostly very expendable process of pattern recognition is used. In the context of this dissertation, the influence of temperature onto the operation behaviour of SAW gas sensors was examined. For this purpose, mass sensitive SAW gas sensors with temperature regulation were produced based on CMOS compatible technology. Beside the possibility of economic mass production, CMOS compatible technology enables the monolithic integration of the devices. Hereby parasitic effects, caused by hybrid integration in the field of high frequencies, could be avoided. Instabilities like temperature drift mostly have a negative influence onto the functionality and behaviour of SAW gas sensors and consequently reduce significantly the sensitivity and stability of the devices. Therefore, the SAW devices produced in this dissertation were equipped with a polysilicon thermal resistor. To measure the surface temperature, a thin film resistor was located on the surface of each device. As a piezoelectric thin film polycrystalline zinc oxide and aluminium nitride were deposited. In order to achieve the required (002)-texture, the reactive HF sputter process as well as the pulsed DC sputter process were used and compared. The results of these examinations have shown, that the pulsed DC sputter process is especially capable to deposit textured thin films. It was possible to deposit strongly textured layers already at room temperature with high deposition rate. The examinations in context of this dissertation have shown, that often a significant increase of the surface temperature is caused by the adsorption of gases. Especially for SAW devices with a positive temperature gradient the variation of temperature causes an increase of transmitted frequency. Compared with the increase of mass by adsorption it should lead to a decrease of transmitted frequency. These two opposite effects lead to a reduction of sensitivity of SAW gas sensors. It could be shown, that a conventionally temperature compensation via electronic mixer circuit is not sufficient to eliminate these effects. So, the applied control of surface temperature was essential. With using the stabilisation of surface temperature, the SAW devices of this dissertation had shown a significant increase of sensitivity. In opposite to the examinations under laboratory conditions, the compounds as well as separate concentrations of a gas mixture are not known in real conditions. Therefore, the principle of pattern recognition is mostly used. By simultaneous use of gas sensors with different sensitivity and selectivity, a pattern of signals can be obtained. Such a structure needs a lot of cavity and further on a more complicated electronic circuit. It could be shown, that a controlled variation of temperature and the resulting temperature coefficients of sensitivity leaded to an additional information about the adsorbed gas component. So, the number of required SAW devices to analyse gas mixtures could be minimized and the selectivity of the SAW gas sensors could be increased significantly. In addition, the well known transient phenomenon of SAW-devices in the range of up to 2 hours could be reduced significantly by heating the devices. Beside these temperature effects, different layer structures and different polymers have been examined in order to cover / protect the SAW devices. An applicative choice of material and layer structure leaded to a significant reduction of drifts and consequently to an increase of long-term stability of SAW gas sensors for the application under real conditions.
机译:通常,表面声波(SAW)气体传感器基于诸如氧化硅或铌酸锂的压电晶体,并且通常采用复杂的技术制造。为了达到高温稳定性,使用了特殊的晶体切割。这些切口通常显示出较小的温度梯度。此外,经常应用通过混合器电路的温度补偿。为了检测不确定的混合气体中的特定成分,使用了非常昂贵的模式识别过程。在本文的背景下,研究了温度对声表面波气体传感器工作性能的影响。为此,基于CMOS兼容技术生产了具有温度调节功能的质量敏感型SAW气体传感器。除了经济地批量生产的可能性外,CMOS兼容技术还可以实现器件的单片集成。因此,可以避免由高频领域中的混合集成引起的寄生效应。诸如温度漂移之类的不稳定性通常会对SAW气体传感器的功能和性能产生负面影响,因此会大大降低设备的灵敏度和稳定性。因此,本文制备的声表面波器件均配备了多晶硅热敏电阻。为了测量表面温度,在每个设备的表面上都放置了一个薄膜电阻器。作为压电薄膜,沉积了多晶氧化锌和氮化铝。为了获得所需的(002)纹理,使用了反应性HF溅射工艺以及脉冲DC溅射工艺并进行了比较。这些检查的结果表明,脉冲直流溅射工艺特别能够沉积有纹理的薄膜。可以在室温下以高沉积速率沉积具有强烈纹理的层。本文的研究表明,表面温度的显着升高通常是由气体的吸附引起的。特别是对于具有正温度梯度的声表面波器件,温度的变化会导致发射频率的增加。与通过吸附增加质量相比,应该导致传输频率的降低。这两个相反的作用导致SAW气体传感器的灵敏度降低。可以看出,常规地通过电子混合器电路的温度补偿不足以消除这些影响。因此,必须控制表面温度。通过表面温度的稳定化,本文的声表面波器件显示出了显着的灵敏度提高。与实验室条件下的检查相反,在真实条件下未知化合物以及混合气体的单独浓度。因此,模式识别的原理被广泛使用。通过同时使用具有不同灵敏度和选择性的气体传感器,可以获得信号模式。这样的结构需要大量的空腔,并且还需要更复杂的电子电路。可以表明,温度的受控变化和所得的灵敏度温度系数导致有关吸附气体成分的其他信息。因此,可以最小化分析气体混合物所需的SAW设备的数量,并且可以显着提高SAW气体传感器的选择性。另外,可以通过加热SAW设备在长达2小时的范围内的众所周知的瞬态现象来减少设备。除了这些温度影响,还研究了不同的层结构和不同的聚合物以覆盖/保护SAW器件。材料和层结构的应用选择导致漂移的显着减少,并因此提高了在实际条件下应用的SAW气体传感器的长期稳定性。

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    Bender Stefan;

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  • 年度 2004
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