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Assessment of rear-surface processing strategies for III-V on Si multijunction solar cells based on numerical simulations

机译:基于数值模拟的Si-多结太阳能电池III-V背面处理策略评估

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摘要

The manufacturing of high-efficiency III-V on Si multijunction solar cells needs the development of hybrid, i.e., adapted to both families of materials, solar cell processing techniques, able to extract the full photovoltaic potential of both the subcells. This fact especially impacts the processing of the silicon rear surface of the tandem, which cannot receive treatments commonly used in the single-junction Si solar cell industry [Al-back surface field (BSF), thermal SiO2, and so on], since these would result in an excessive thermal load that would deteriorate the III-V upper layers (top cell, tunnel junction, and buffer layer). However, the Si bottom cell requires an advanced design with good rear passivation, a good ohmic contact, and good carrier selectivity, so that its contribution to the efficiency of the tandem is maximized. Accordingly, in this paper, several low-temperature compatible rear-surface passivation techniques for the Si bottom subcell in a monolithic III-V/Si tandem solar cell are explored. In particular, aluminum BSFs, passivated emitter and rear cell (PERC)-like architecture, passivated emitter and rear locally diffused (PERL)-like architecture formed with low thermal loads, and heterojunction with intrinsic thin layer (HIT)-like processes are assessed using numerical simulations, and a comparison of the Si bottom cell performance for the mentioned alternatives in a GaAsP/Si dual-junction solar cell is presented.
机译:在Si多结太阳能电池上制造高效III-V电池需要发展混合动力技术,即适用于两种材料族,太阳能电池加工技术,能够提取两个子电池的全部光伏电势。这个事实特别影响了串联的硅背面的处理,该串联的硅背面无法接受单结硅太阳能电池行业常用的处理[Al背面场(BSF),热SiO2等],因为这些会导致过大的热负荷,从而使III-V上层(顶层电池,隧道结和缓冲层)劣化。但是,Si底部电池需要具有良好的后钝化,良好的欧姆接触和良好的载流子选择性的先进设计,以便最大程度地提高其对串联效率的贡献。因此,在本文中,探索了用于单片III-V / Si串联太阳能电池中的Si底部子电池的几种低温兼容的背面钝化技术。特别是,评估了铝BSF,钝化的发射极和后电池(PERC)架构,钝化的发射极和后局部扩散(PERL)架构(具有低热负荷)以及具有固有薄层(HIT)流程的异质结使用数值模拟,并比较了GaAsP / Si双结太阳能电池中上述替代品的Si底部电池性能。

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