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Rhéologie des matériaux pâteux : vers un continuum des régimes solide et liquide. Application aux boues résiduaires

机译:糊状材料的流变学:朝向固体和液体状态的连续体。应用于污泥

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摘要

In a context of constant increasing volumes of wastewater treatment sludge, optimizing the treatment of sludge appears to be crucial. Each step of treatment and transportation involves flows. It appears necessary to understand and predict these flows in order, for example, to estimate pressure drops in pipes or to size properly pumping facilities. In a physical point of view, sludge can be considered as a suspension of particles in a gel. Thus, its rheological behaviour presents significant similarities to that of colloidal suspensions of polymeric gels. These three types of materials, i.e. wastewater treatment sludge, colloidal suspensions and polymeric gels, present a complex rheological behaviour which depend on both time and the applied solicitation. They exhibit a dual behaviour, solid at low shear stresses, and liquid when the applied shear stress is high. The solid-liquid behaviour is generally modelled by defining a critical shear stress or a critical strain, supposed to be the limit between the solid and liquid regimes. Nevertheless, this concept implies an abrupt transition, unlike experimental observations showing a continuous and progressive transition. The study of the literature permitted to highlight the need to improve the understanding and modelling of the solid-liquid transition. Moreover, it appears necessary to unify the description of the solid and liquid regime in a unique model, in order to link a mathematical continuity with thecontinuous and progressive nature of the physical phenomenon to model. The study of the results available in the literature permited us to build a unique mathematical model to describe both the solid behaviour and the liquid behaviour of the studied materials. The assumptions made from the literature results have thus been experimentally validated. The proposed model is based on the decomposition of the compliance of the material in the sum of a solid contribution and a liquid contribution, depending on time, the applied solicitation and the story of the material.This model permits a unique description of solide and liquid regimes of the material, taking into account the existence of a residual elasticity at high shear stresses, and a viscous dissipation for low shear stresses, in accordance with experimental results. This work permitted to highlight the fact that the solid-liquid transition mecanism is controlled by the compliance of the material, and not the shear stress or the strain. Moreover, it opened the way to a new way of understanding the thixotropy and the solid-liquid transition of pasty materials. Thus, the behaviour of a pasty material is controlled by two parameters : a plateau elastic modulus corresponding to a totally structured state, and an infinite viscosity corresponding to a totally destructured state. These parameters intrinsic to the material are pondered by the evolutions of the microstructure, leading to a competition between elastic and viscous effects. Thus, the difference between the power law behaviour and the Herschel-Bulkley behaviour can be simply explained by the apparition of elastic effects that can’t be neglected.
机译:在废水处理污泥量不断增加的背景下,优化污泥处理似乎至关重要。处理和运输的每个步骤都涉及流程。似乎有必要理解和预测这些流量,以便例如估计管道中的压降或适当地确定泵设备的尺寸。从物理角度来看,污泥可被视为颗粒在凝胶中的悬浮液。因此,其流变行为与聚合物凝胶的胶体悬浮液具有显着的相似性。这三种类型的材料,即废水处理污泥,胶体悬浮液和聚合物凝胶,表现出复杂的流变行为,这取决于时间和所施加的诱导。它们表现出双重特性,在低剪切应力下为固体,而在施加的高剪切应力下为液体。通常通过定义临界剪切应力或临界应变来建模固液行为,该临界剪切应力或临界应变被认为是固液状态之间的极限。然而,与实验观察到的连续不断的过渡不同,该概念暗示了突然过渡。对文献的研究允许强调需要改进对固液过渡的理解和建模。此外,似乎有必要在一个独特的模型中统一对固体和液体状态的描述,以便将数学上的连续性与要建模的物理现象的连续性和渐进性联系起来。对文献中可用结果的研究使我们能够建立一个独特的数学模型来描述所研究材料的固体行为和液体行为。因此,从文献结果中得出的假设已通过实验验证。所提出的模型基于材料的依从性在固体成分和液体成分的总和中的分解,具体取决于时间,应用的招标和材料的情况,该模型可以对固体和液体进行独特的描述根据实验结果,考虑到材料在高剪切应力下的残余弹性以及低剪切应力下的粘性耗散,确定了材料的弹性模量。这项工作突出了一个事实,即固液过渡机制是由材料的柔韧性控制的,而不是由剪切应力或应变控制的。此外,它为了解糊状材料的触变性和固液转变开辟了一条新途径。因此,糊状材料的行为由两个参数控制:对应于完全结构化状态的平稳弹性模量和对应于完全变形状态的无限粘度。材料固有的这些参数由微观结构的演变来考虑,从而导致弹性和粘性效应之间的竞争。因此,幂律行为和Herschel-Bulkley行为之间的差异可以用不可忽视的弹性效应来简单解释。

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    Quignon-Tosoni Justine;

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  • 年度 2015
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