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Identification of fine (PM1) and coarse (PM10-1) sources of particulate matter in an urban environment

机译:在城市环境中识别精细(PM1)和粗糙(PM10-1)颗粒物源

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摘要

PM10 and PM1 samples were collected at an urban site in southeastern Spain during 2006-2010. The chemical composition of all samples has been determined and analyzed by Positive Matrix Factorization (PMF) technique for fine and coarse source identification. The PMF results have been analyzed for working and non-working days in order to evaluate the change in PM sources contribution and possible future abatement strategies. A decreasing trend in PM10 levels and in its constituents has been observed, being partly associated to a reduction in anthropogenic activities due to the economic crisis. The use of fine and coarse PM in the PMF analysis allowed us for the identification of additional sources that could not be identified using only one size fraction. The mineral dust source was identified in both fractions and comprised 36 and 22% of the total mass in the coarse and fine fractions, respectively. This high contribution of the mineral source to the fine fraction may be ascribed to contamination of the source profile. The regional re-circulation source was traced by secondary sulfate, V and Ni. It was the most important source concerning PM1 mass concentration (41% of the total mass in this fraction). Although V and Ni are commonly associated to fuel oil combustion the seasonality of this source with higher concentrations in summer compared with winter suggest that the most important part of this source can be ascribed to regional pollution episodes. A traffic exhaust source was identified but only in the fine fraction, comprising 29% of the fine mass. The celestite mines source associated with nearby open-pit mines was typified by strontium, sulfate and mineral matter. PM10-1 levels were higher in working days, whereas PM1 levels remained fairly constant throughout the whole week. As a conclusion, traffic seems to be the main source to target in Granada.
机译:在2006年至2010年期间,在西班牙东南部的一个城市地点收集了PM10和PM1样品。已通过正矩阵分解(PMF)技术确定并分析了所有样品的化学成分,以进行精细和粗略的来源鉴定。已对PMF结果进行了工作日和非工作日分析,以评估PM来源贡献的变化以及未来可能的减排策略。已观察到PM10含量及其成分的下降趋势,部分与经济危机导致的人为活动减少有关。在PMF分析中使用精细和粗糙的PM使我们能够识别仅使用一个尺寸分数就无法识别的其他来源。在这两个馏分中均确定了矿物粉尘源,粗粉和细粉分别占总质量的36%和22%。矿物源对细颗粒的高贡献可能归因于源剖面的污染。二次硫酸盐,钒和镍可以追溯到区域再循环源。这是有关PM1质量浓度的最重要来源(此部分中总质量的41%)。尽管钒和镍通常与燃油燃烧有关,但与冬季相比,夏季这种浓度较高的来源的季节变化表明,该来源的最重要部分可归因于区域污染事件。确定了一个交通尾气排放源,但仅占细小部分,占细小质量的29%。与附近露天矿有关的天青石矿源以锶,硫酸盐和矿物质为代表。在工作日中,PM10-1水平较高,而整周中PM1水平保持相当稳定。结论是,交通似乎是格拉纳达的主要目标客源。

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