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Investigation of host liquid crystal composition on polymerudstabilised blue phase properties

机译:聚合物上液晶主体液晶组成的研究稳定的蓝相特性

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摘要

Polymer stabilised blue phase liquid crystals (PSBPLCs) have been investigated for photonics and display applications for the following reasons: optical isotropy in the dark state, ease of fabrication due to the omission of the alignment layer, and sub-millisecond response length. Major barriers to the commercialisation of PSBPLCs are: hysteresis, residual birefringence, and most significantly, high driving voltage. We have chosen to lower the driving voltage through optimization of the mixture (host LC, chiral dopant and monomer). In this paper, investigation of the contribution of the host liquid crystal to the phase stability and electro-optic characteristics of the PSBP will be discussed. The following cases have been investigated: a) A three component host liquid crystal (E8, PE-sCNF (4- Cyano-3-fluorophenyl 4-pentyl benzoate) and CPP-3FF (4-(trans-4-n-propyl cyclohexyl)-3',4'-difluoro-l,l'- biphenyl), LCC Corporation, Japan). For a ratio of E8:PE-CNF:CPP-3FF of 5:3:2, a large BPI window of >SO.4°C and low hysteresis was achieved, but the driving voltage was 79V, and b) A single host liquid crystal, 80CB with chiral dopant Clsl S. For a ratio for 80CB:CBls of 1:1, this mixture demonstrated a significantly lower driving voltage of 6SV, but exhibited a smaller BPI window of >27°C. Decrease in the ratio of 80CB:CBls also induced the presence of a BPII phase in the mixture. A single host liquid crystal has the advantage of simplicity of composition, and lowered driving voltage. However, the hysteresis and blue phase temperature range needs to be optimised. This investigation concludes upon the suggestion of liquid crystal characteristics which optimises the blue phase temperature range, low hysteresis, switching times and driving voltage.
机译:由于以下原因,已经研究了聚合物稳定的蓝相液晶(PSBPLC)在光子学和显示应用中的应用:处于黑暗状态的光学各向同性,由于缺少取向层而易于制造以及亚毫秒级的响应长度。 PSBPLC商业化的主要障碍是:滞后,残留双折射以及最重要的是高驱动电压。我们选择通过优化混合物(主体LC,手性掺杂剂和单体)来降低驱动电压。本文将讨论基质液晶对PSBP的相稳定性和电光特性的影响。研究了以下情况:a)三组分主体液晶(E8,PE-sCNF(4-氰基-3-氟苯基4-戊基苯甲酸酯)和CPP-3FF(4-(反式-4-正丙基环己基) )-3′,4′-二氟-1,1′-联苯,日本LCC公司)。对于E8:PE-CNF:CPP-3FF的比例为5:3:2的情况,BPI窗口大于SO.4°C,磁滞低,但驱动电压为79V,并且b)单个主机液晶,具有手性掺杂剂Clsl S的80CB。对于80CB:CBls的比例为1:1,此混合物显示出较低的驱动电压6SV,但显示的BPI窗较小,> 27°C。 80CB:CBls比值的降低也引起了混合物中BPII相的存在。单一主体液晶具有组成简单和降低驱动电压的优点。但是,磁滞和蓝相温度范围需要优化。这项研究基于对液晶特性的建议,该特性可优化蓝相温度范围,低滞后,开关时间和驱动电压。

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