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Novel Synthetic-Based Drilling Fluid through Enzymatic Interesterification of Canola Oil

机译:通过酶活化油菜油的新型合成钻井液

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摘要

Over the years, the oil industries have avoided aromatic, naphthenic, and paraffinic oils as drilling mud base fluids principally because of their detrimental environmental issues on pelagic and benthic marine ecosystems as a result of their toxicity and nonbiodegradability coupled with the possible deterioration of the oil itself and the rubber parts of the drilling equipment because the aromatic hydrocarbons present in the oil have a tendency to dissolve/damage elastomers present in rubber. Hence, possible insights into how to chemically and/or physically produce synthetic base drilling fluids whose cuttings are nontoxic, readily biodegradable, environmentally friendly, and of nonpetroleum source become imperative. In this study, enzymatic interesterification of canola oil was done with ethanol by using enzyme lipase as catalyst under optimum conditions of temperature and pressure and the physicochemical properties of the produced ester were evaluated and compared with that of diesel and a synthetic hydrocarbon base fluid (SHBF). Results show that the specific gravity, kinematic viscosity, dynamic viscosity, and surface tension of canola oil were reduced by 5.50%, 94.74%, 95.03%, and 9.38%, respectively, upon enzymatic interesterification to conform to standard requirements. Similarly, increased |mud ability to pump fluids and possibility of cold temperature environment can be achieved with the reduction in pour point and cloud point, respectively, of the produced canola oil ester. Finally, the produced ester showed no aromatic content as confirmed from its FTIR analysis which indicates its nontoxicity, biodegradability, and environmental friendliness.
机译:多年来,石油产业避免了芳香,环烷体和石蜡油,因为由于它们的毒性和非耐脱果生态系统上的毒性和底栖海洋生态系统上的有害环境问题,因此毒性和非脱节性与油的可能性劣化本身和钻井设备的橡胶部分,因为油中存在的芳烃具有溶解/损伤橡胶的弹性体的趋势。因此,可以在如何进行化学和/或物理生产的综合基础钻井液中的可能见解,其切屑无毒,易于生物降解,环保和非单体源变得势在必行。在该研究中,通过使用酶脂肪酶在温度和压力的最佳条件下使用酶脂肪酶作为催化剂,并将产生的酯的物理化学性能与柴油和合成烃基碱(SHBF(SHBF)进行评价并进行比较,并将其在催化剂中用乙醇进行酶的酶活化。 )。结果表明,在酶活化以符合标准要求的情况下,CANOLA油的比重,CANOLA油的比重,运动粘度,动态粘度和表面张力分别降低了5.50%,94.74%,95.03%和9.38%。类似地,通过分别的浇注点和浊点的减少,可以实现增加的泵流体的泥浆能力和冷温度环境的可能性。最后,所产生的酯没有从其FTIR分析中证实的芳族含量,这表明其无毒,生物降解性和环境友好性。

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