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Weathering Stability and Durability of Birch Plywood Modified with Different Molecular Weight Phenol-Formaldehyde Oligomers

机译:用不同分子量酚醛 - 甲醛低聚物改性桦木胶合板的风化稳定性和耐久性

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摘要

This study investigated the effect of phenol-formaldehyde (PF) resin treatment on the weathering stability and biological durability of birch plywood. Silver birch (Betula pendula) veneers were vacuum-pressure impregnated with four different PF resins with average molecular weights (Mw) of 292 (resin A), 528 (resin B), 703 (resin C), and 884 g/mol (resin D). The aging properties of PF resin modified birch plywood were analyzed using artificial weathering with ultraviolet (UV) light, UV and water spray, and weathering under outdoor conditions. The same combinations of PF-treated plywood specimens were then tested in soil-bed tests to determine their resistance against soft-rot wood decay. It was not possible to compare weathering processes under artificial conditions to processes under outdoor conditions. However, the weathering stability of birch plywood treated with PF resins A, B, and C, scored better than plywood treated with commercial resin D (regardless of solid content concentration [%]). Results from unsterile soil bed tests showed improvements in resistance to soft-rot wood decay compared to untreated plywood and solid wood. Mass loss [%] was lowest for birch plywood specimens treated with resin of highest solid content concentration (resin D, 20%). Provisional durability ratings delivered durability class (DC) ratings of 2–3, considerably improved over untreated solid wood and untreated birch plywood (DC 5).
机译:本研究研究了酚醛 - 甲醛(PF)树脂处理对桦木胶合板的耐候性和生物耐久性的影响。银桦(Betula Pendula)贴面是浸渍有四种不同PF树脂的真空压力,其平均分子量(Mw)为292(树脂A),528(树脂B),703(树脂C)和884g / mol(树脂) d)。使用紫外(UV)光,UV和水喷雾的人工风化分析PF树脂改性桦木胶合板的老化性能,以及在室外条件下风化。然后在土床测试中测试相同的PF处理的胶合板标本的组合,以确定它们对软腐木衰减的抵抗力。不可能将风化过程与人工条件下的耐候过程进行比较,以在室外条件下进行。然而,用PF树脂A,B和C处理的桦木胶合板的风化稳定性,比用商业树脂D处理的胶合板更好地得分(无论固体含量浓度为])。与未处理的胶合板和实木相比,取消土壤床试验的结果表明,与未处理的胶合板和实木相比,对软腐木衰减的抗性的改善。用最高固体含量浓度(树脂D,20%)处理的桦木胶合板标本的质量损失[%]最低。临时耐久性额定额定耐久性等级(DC)额定值2-3,对未处理的实体木材和未处理的桦木胶合板(DC 5)相当改善。

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