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Hydrogen sulphide exposure in waste water treatment

机译:废水处理中的硫化氢暴露

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摘要

Abstract Background The aims of this study was to assess exposure to hydrogen sulphide (H2S) among waste water treatment workers (WWWs), and achieve a better measure of the risks of H2S exposure than only using the eight-hour average value and the ceiling value because the exposure pattern of H2S for WWWs is dominated by short-term peaks. Methods Ninety-three measurements of H2S from 56 WWWs in three cities and three rural areas were collected. All exposure measurements were carried out from the start of the day until lunch time (sampling time 4–5 h) when most of the practical work was performed. The type of tasks and extent of flushing were registered. H2S was measured using direct-reading instruments with logging: OdaLog L2/LL, Dräger X-am 5000 and Dräger Pac 7000 (0.1–200 ppm). Number and duration of peaks for different work tasks, seasons, places and extent of flushing were combined in an exposure index (IN), and evaluated in a mixed-model analysis, building a model aimed to predict exposure for different job tasks. Results Nine Percent (8 of 93) of all H2S measurements have peaks above 10 ppm; in addition, 15% (14 of 93) have peaks of 5–10 ppm, 35% (33 of 93) have peaks of 1–5 ppm and 65% (62 of 93) have peaks of 0.1–1 ppm. 29% of the measurements of hydrogen sulphide showed no registered level > 0.1 ppm. From the mixed-model analyses we see that exposure level, expressed as H2S index IN, varied between places, work type, season and degree of flushing. For the work in a plant in the capital, the exposure index varied from 0.02 for working in spring doing some flushing, to 0.7 for working at the same plant in winter doing flushing more than three times or more than 10 min. Collecting sewage from cesspools in city 2 in winter doing a lot of flushing gave a hydrogen sulphide index of 230. Conclusions The use of a H2S index, taking into consideration peak height, duration and number of peaks, could be a tool for exposure assessment for H2S.
机译:摘要背景本研究的目的是评估废水处理工人(WWWS)中的硫化氢(H2S)的暴露,并实现比仅使用八小时平均值和天花板值的H2S暴露风险的更好衡量标准因为WWWS的H2S的曝光模式由短期峰占主导地位。方法收集了三个城市和三个农村地区56个wwws的93次H2S测量。所有曝光测量都从一天开始,直到大多数实际工作进行午餐时间(采样时间4-5小时)。注册了冲洗的任务类型和程度。使用具有测井的直接读书仪器测量H2S:Odalog L2 / LL,DRÄGERX-AM 5000和DRÄGERPAC7000(0.1-200ppm)。不同工作任务的峰值的数量和持续时间,季节,地方和冲洗程度的曝光指数(in)组合,并在混合模型分析中进行评估,建立一个模型,该模型预测不同的工作任务的曝光。结果所有H2S测量的九倍(8个中的8个)的峰值高于10ppm;此外,15%(14个中的10个)具有5-10ppm的峰,35%(33个of 93)具有1-5ppm的峰,65%(62个,共93个)的峰具有0.1-1ppm的峰。硫化氢的29%的测量显示没有注册水平> 0.1ppm。从混合模型分析中,我们看到暴露水平,表达为H2S指数,在地点,工作类型,季节和冲洗程度之间变化。对于在资本的工厂的工作中,曝光指数从0.02次在春天工作时变化,在冬季在同一植物中工作时,在冬季工作的0.7次,以三倍以上或超过10分钟。从Cesspools中收集污水处理冬季冬季进行了大量冲洗,给出了硫化氢指数为230.结论使用H2S指数,考虑到峰值高度,持续时间和峰值的峰值,可能是用于接触评估的工具H2S。

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