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Production of Organic Nitrates from Hydroxyl and Nitrate Radical Reaction with Propylene

机译：从羟基和硝酸盐与丙烯自由基反应生成有机硝酸盐

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Measurements of the gas-phase production rates of alpha-nitratoacetone, propylene glycol dinitrate, 2-hydroxy propyl nitrate, and 2-nitrato propyl alcohol (2-NPA) in a C3H6/N2O5/air dark reaction and a C3H6/NOX/air irradiation are reported. The probable operative reaction mechanisms are discussed and the branching ratios for peroxy radical reaction with no via RO2 + NO -> RONO2 versus RO2 + NO -> RO +NO2 are estimated for CH3CH(OO)CH2OH and CH3CH(OH)CH2OO radicals.

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Shepson, P. B. ; Edney, E. O. ; Kleindienst, T. E. ; Pittman, J. H. ; Namie, G. R.;
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年度 1985
页码 1-8
总页数 8
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Nitrates; Reprints;

机译：硝酸盐;重印;

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1. Proposed chemical mechanisms leading to secondary organic aerosol in the reactions of aliphatic amines with hydroxyl and nitrate radicals [J] . Derek J. Price, Christopher H. Clark, Xiaochen Tang, Atmospheric environment . 2014,第Octa期

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2. Investigation of dark condition nitrate radical- and ozone-initiated aging of toluene secondary organic aerosol: Importance of nitrate radical reactions with phenolic products [J] . Atmospheric environment . 2019,第DECa期

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3. Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of α-pinene and β-pinene [J] . Takeuchi Masayuki, Ng Nga L. Atmospheric Chemistry and Physics Discussions . 2019,第19期

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4. Reactivity of semivolatile organic compounds (SVOCs) with hydroxyl radicals, nitrate radicals, and ozone in indoor air [C] . Wei W, Mandin C, Ramalho O Joint annual meeting of the International Society of Exposure Science and the International Society for Environmental Epidemiology . 2019

机译：半挥发性有机化合物（SVOC）与室内空气中的羟基自由基，硝酸盐自由基和臭氧的反应性
5. Laboratory and Ambient Studies of the Products of Gas-Phase Hydroxyl and Nitrate Ion Radical-Initiated Reactions with Selected PAHs. [D] . Zimmermann, Kathryn Jean. 2012

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6. Volatile organic compound conversion by ozone hydroxyl radicals and nitrate radicals in residential indoor air: Magnitudes and impacts of oxidant sources [O] . Michael S. Waring, J. Raymond Wells -1

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7. Chemical Composition and Hydrolysis of Organic Nitrate Aerosol Formed from Hydroxyl and Nitrate Radical Oxidation of α-pinene and β-pinene [O] . Masayuki Takeuchi, Nga L. Ng 2019

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8. Production of Organic Nitrates from Hydroxyl and Nitrate Radical Reaction with Propylene [R] . P. B. SHEPSON, E. O. EDNEY, T. E. KLEINDIENST 1985

机译：从羟基和硝酸盐与丙烯自由基反应生成有机硝酸盐

Production of Organic Nitrates from Hydroxyl and Nitrate Radical Reaction with Propylene

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