New Bicyclic Nitrogen Tetroxide Cation, NO4(+) Has a Low Decomposition Energy.

摘要

Nitrogen oxide cations, such as NO2(+) and NO(+), are strong oxidizers and useful components for ionic High Energy Density Materials (HEDM) 1. Their energy content and oxidizing power increase with increasing oxidation state of the nitrogen atom and the number of oxygen ligands. In our search for related, halogen-free, highly energetic cations we have became interested in the bicyclic NO4(+)(I).