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Internal Exchange in New Group III Metalloborane Derivatives. (CH3)2ALB3H8 and (CH3)2GaB3H8

机译:新III族金属硼烷衍生物的内部交换。 (CH3)2aLB3H8和(CH3)2GaB3H8

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摘要

Reaction of (CH3)2AlCl and (CH3)2GaCl with salts of the B3H8(-) anion produces (CH3)2AlB3H8 and (CH3)2GaB3H8, respectively, in good yields. The nmr spectral characteristics are unusual and suggest several internal exchange processes. (Author)

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