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Reaction of Magnesium with cis-1,3,5-Tris(Bromomethyl)Cyclohexane. Evidence for a Soluble Tri-Grignard

机译：镁与顺式-1,3,5-三（溴甲基）环己烷的反应。可溶性Tri-Grignard的证据

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The reaction of magnesium with cis-1,3,5-tris(bromomethyl)cyclohexane in tetrahydrofuran gives good yields of a soluble tri-Grignard reagent. This intermediate was characterized by reactions with water, triimethylchlorosilane and methyltrichlorosilane.

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Boudjouk, P.; Sooriyakumaran, R.; Kapfer, C. A.;
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年度 1985
页码 p.1-4
总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Synthesis(Chemistry); Grignard reagents; Magnesium; Hexanes; Cyclic compounds; Bromine compounds; Methyl radicals; Silicon compounds; Reprints;

机译：合成（化学）;格氏试剂;镁;己烷;环状化合物;溴化合物;甲基;硅化合物;重印;

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1. Crystal structures of 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene and 2,4,6-trimethyl-1,3,5-tris(4-oxymethyl-1-formylphenyl)benzene [J] . Arockia Samy N., Alexander V. Journal of chemical crystallography . 2012,第2期

机译：1,3,5-三（溴甲基）-2,4,6-三甲基苯和2,4,6-三甲基-1,3,5-三（4-氧甲基-1-甲酰基苯基）苯的晶体结构
2. Crystal Structures of 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene and 2,4,6-Trimethyl-1,3,5-tris(4-oxymethyl-1-formylphenyl)benzene [J] . Journal of Chemical Crystallography . 2012,第2期

机译：1,3,5-三（溴甲基）-2,4,6-三甲基苯和2,4,6-三甲基-1,3,5-三（4-氧甲基-1-甲酰基苯基）苯的晶体结构
3. An Investigation of Staudinger Reactions Involving cis-1,3,5-Triazidocyclohexane and Tri(alkylamino)phosphines [J] . Xiaodong Liui, Natesan thirupathi, Lia A.Guzei, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第23期

机译：涉及顺式1,3,5-三叠氮环己烷和三（烷基氨基）膦的斯托丁格反应的研究
4. Electrosynthesis of Metal-Organic Frameworks (MOFs)Based on Nickel(II) and Benzene 1,3,5-Tri Carboxylic Acid (H3BTC): An Optimization Reaction Condition [C] . W W Lestari, I D Winarni, F Rahmawati Joint Conference on Chemistry . 2017

机译：基于镍（II）和苯1,3,5-三羧酸（H3BTC）的金属 - 有机框架（MOF）的电气结合：优化反应条件
5. Tris(cis-2-hydroxycyclohexane-1,3,5-triaminium) hydrogen sulfate octachloride dihydrate [O] . Christian Neis, Günter J. Merten, Kaspar Hegetschweiler 2015

机译：三（顺-2-羟基氧基环己烷-1,3,5-三）硫酸氢八氯二水合物
6. Poly[(μ6-benzene-1,3,5-tricarboxylato-κ6 O 1:O 1′:O 3:O 3′:O 5:O 5′)tris(N,N-dimethylformamide-κO)tris(μ3-formato-κ2 O:O′)trimagnesium(II)] [O] . Yeh, Chun-Ting, Liu, Hsin-Kuan, Lin, Chia-Jing, 2010

机译：聚[（μ6-苯-1,3,5-三羧基-κ6 Ø 1：O 1 .： 3：O 3 .： 5：O 5'）tris（N，N-二甲基甲酰胺-κO）tris（μ3-甲酰-κ2 O：O'）三镁（II）]

Reaction of Magnesium with cis-1,3,5-Tris(Bromomethyl)Cyclohexane. Evidence for a Soluble Tri-Grignard

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