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Diffusion of two molecular species in a crowded environment: theory and experiments

机译:在拥挤的环境中两种分子种类的扩散:理论和实验

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摘要

Diffusion of a two component fluid is studied in the framework of differential equations, but where these equations are systematically derived from a well-defined microscopic model. The model has a finite carrying capacity imposed upon it at the mesoscopic level and this is shown to lead to nonlinear cross diffusion terms that modify the conventional Fickean picture. After reviewing the derivation of the model, the experiments carried out to test the model are described. It is found that it can adequately explain the dynamics of two dense ink drops simultaneously evolving in a container filled with water. The experiment shows that molecular crowding results in the formation of a dynamical barrier that prevents the mixing of the drops. This phenomenon is successfully captured by the model. This suggests that the proposed model can be justifiably viewed as a generalization of standard diffusion to a multispecies setting, where crowding and steric interferences are taken into account.
机译:在微分方程的框架中研究了两组分流体的扩散,但是这些方程是从定义明确的微观模型中系统得出的。该模型在介观水平上具有有限的承载能力,这表明会导致非线性交叉扩散项,从而改变了传统的Fickean图片。在回顾了模型的推导之后,描述了为测试模型而进行的实验。已经发现,它可以充分解释两个密墨滴在充满水的容器中同时演化的动力学。实验表明,分子拥挤导致形成动态屏障,从而阻止液滴混合。该现象已被模型成功捕获。这表明,所提出的模型可以合理地视为标准扩散到多物种环境的一般化,其中考虑了拥挤和空间干扰。

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