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Characterization and Kinetics of Siberian and Tatarstan Regions Crude Oils Using Differential Scanning Calorimetry

机译:西伯利亚和Ta斯坦地区原油的差示扫描量热法表征与动​​力学

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摘要

In this study, nonisothermal kinetics and thermal analysis of Siberian and Tatarstan regions crude oils is studied by differential scanning calorimetry (DSC) at different heating rates. DSC curves revealed two reaction regions in the temperature range of 20-600 degrees C, known as low and high temperature oxidation, respectively. Three different kinetic methods (ASTM, Borchardt and Daniels, and Roger and Morris) were used to determine the kinetic parameters of the samples and it was observed that the activation energy values are varied.
机译:在这项研究中,通过差示扫描量热法(DSC)在不同的加热速率下研究了西伯利亚和Ta斯坦地区原油的非等温动力学和热分析。 DSC曲线揭示了在20-600℃的温度范围内的两个反应区域,分别称为低温氧化和高温氧化。三种不同的动力学方法(ASTM,Borchardt和Daniels以及Roger和Morris)被用来确定样品的动力学参数,并且观察到活化能值是变化的。

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