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New sesquiterpenes from Euonymus europaeus (Celastraceae).

机译:欧洲卫矛(Ceustraceae)的新倍半萜。

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摘要

A new sesquiterpene evoninate alkaloid (1), and two sesquiterpenes (2, 3) with a dihydro-beta-agarofuran skeleton, along with three known sesquiterpenes (4-6), were isolated from the seeds of Euonymus europaeus. Their structures were elucidated by high resolution mass analysis, and one- and two-dimensional (1D and 2D) NMR spectroscopy, including homonuclear and heteronuclear correlation [correlation spectroscopy (COSY), rotating frame Overhauser enhancement spectroscopy (ROESY), heteronuclear single quantum coherence (HSQC), and heteronuclear multiple bond correlation (HMBC)] experiments.
机译:从欧洲卫矛的种子中分离出一种新的倍半萜烯生物碱(1)和两个具有二氢-β-agarofuran骨架的倍半萜烯(2、3)以及三个已知的倍半萜烯(4-6)。通过高分辨率质量分析以及一维和二维(1D和2D)NMR光谱阐明了它们的结构,包括同核和异核相关[相关光谱(COSY),旋转框架Overhauser增强光谱(ROESY),异核单量子相干性(HSQC)和异核多键相关(HMBC)实验。

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