IMPROVED SYNTHESIS OF METHYL 4,6-O-BENZYLIDENE-3-CYANO-2,3-DIDEOXY-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE AND METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-C-FORMYL-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSI DE

Spanevello RA.; Pellegrinet SC.

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IMPROVED SYNTHESIS OF METHYL 4,6-O-BENZYLIDENE-3-CYANO-2,3-DIDEOXY-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE AND METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-C-FORMYL-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSI DE

机译：改进的4,6-O-苄基-3-甲基-氰基-2,3-二氧-α-D-赤-己基-2-烯丙基氨基化物和甲基4,6-O-苄基-2,3-二甲氧基-3的合成-C-甲酰基-α-D-赤藓族-己二-2-烯吡喃

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Simple and efficient route to the title compounds by using diethyl aluminium cyanide in benzene for the epoxide ring opening and the electrophilic assistance of LiClO4 during the isomerization-elimination process. [References: 10]

机译：通过在苯中使用二乙基氰化铝用于环氧化物开环和异构化消除过程中的LiClO4的亲电子助剂，可以简单有效地制备标题化合物。 [参考：10]

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《Synthetic Communications》 |1995年第22期|共8页
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Spanevello RA.; Pellegrinet SC.;
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1. IMPROVED SYNTHESIS OF METHYL 4,6-O-BENZYLIDENE-3-CYANO-2,3-DIDEOXY-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE AND METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-C-FORMYL-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSI DE [J] . Spanevello RA., Pellegrinet SC. Synthetic Communications . 1995,第22期

机译：改进的4,6-O-苄基-3-甲基-氰基-2,3-二氧-α-D-赤-己基-2-烯丙基氨基化物和甲基4,6-O-苄基-2,3-二甲氧基-3的合成-C-甲酰基-α-D-赤藓族-己二-2-烯吡喃
2. Synthesis, separation and configuration determination of diastereoisomers of (R,S)-1-methyl-3-[3-(aryl)-1,2,4-oxadiazol-5-yl] propyl 2,3-dideoxy-alpha-D-erythro-hex-2-enopyranosides [J] . Srivastava RM, de Freitas JR, da Silva MJ, Tetrahedron . 2004,第47期

机译：（R，S）-1-甲基-3- [3-（芳基）-1,2,4-恶二唑-5-基]丙基2,3-二脱氧-α-D的非对映异构体的合成，分离和构型测定-赤-己基-2-烯吡喃糖苷
3. Synthesis of methyl 4,6-O-benzylidene-2,3-dideoxy-5-thio-beta-DL-threo-hex-2-enopyranoside via hetero-Diels-Alder reaction and unusual stabilities of 1,5-anhydro-4,6-O-benzylidene 2,3-dideoxy-5-thio-DL-threo-hex-2-enitol [J] . Watanabe Y, Sakakibara T Tetrahedron . 2009,第3期

机译：杂Diels-Alder反应合成1,5-脱水-4的甲基4,6-O-亚苄基-2,3-二脱氧-5-硫代-β-DL-苏-己-2--2-吡喃糖苷，6-O-亚苄基2,3-二脱氧-5-硫代-DL-苏-己-2-烯醇
4. Study on the Synthesis and Application of a Material 1-2-Methyl-5-Phenyl-3-Thienyl-2-2-Methyl-5-(3-Aldehyde-4-Methoxy)-3-Thienyl Perfluorocyclopentene [C] . Rui-Min LU, Shu-Ying LI, Shi-Qiang CUI International Conference on Advanced Material Research and Application . 2017

机译：物质1- 2-甲基-5-苯基-3-噻吩基 -2- 2-甲基-5-（3-醛-4-甲氧基）-3-噻吩基全氟环戊烯的合成与应用研究
5. Part I Shorter and Improved Access to the Key Tetracyclic Core of C-19 Methyl Substituted Bioactive Sarpagine-Macroline-Ajmaline Indole Alkaloids via a New Ambidextrous Asymmetric Pictet-Spengler Reaction Beginning from Either D-(+)- or L-(-)-Tryptophan Part II the Total Synthesis of a Number of Bioactive C-19 Methyl Substituted Macroline-Sarpagine Indole Alkaloids Including Macrocarpines A-g, Talcarpine, N(4)-Methyl- N(4),21-Secotalpinine, Deoxyperaksine, Dihydroperaksine, Talpinine, O-Acetyltalpinine, as Well as N(4)-Methyltalpinine [D] . Rahman, Md Toufiqur 2018

机译：第一部分通过D-（+）-或L-（-）-开始的新的两性不对称Pictet-Spengler反应，更短和更好地利用C-19甲基取代的生物活性Sarpagine-Macroline-Ajmaline吲哚生物碱的关键四环核。色氨酸第二部分，包括大果胶Ag，塔卡品平，N（4）-甲基-N（4），21-四氢松油碱，脱氧peraksines，dihydroperaksine，Talpinine，O -乙酰基talpinine以及N（4）-甲基talpinine
6. Synthesis and crystal structure of ((E)-{2-(E)-(4-hydroxynaphthalen-1-yl)methylidenehydrazin-1-yl}(methylsulfanyl)methylidene)azanium hydrogen sulfate monohydrate [O] . Oussama Nehar, Samira Louhibi, Leila Boukli-Hacene, 2016

机译：一水合（（E）-{2-（E）-（4-羟基萘-1-基）甲基亚萘基肼-1-基}（甲基硫烷基）甲基亚基）硫酸氢铵的合成及晶体结构
7. Preparation of Methyl 2,3-Anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside and SomeC2-Branched-Chain Derivatives of Methyl 4,6-O-Benzylidene-2,3-dideoxy-3-nitro-β-D-glucopyranoside [O] . Tohru Sakakibara, Satoru Kumazawa, Toshio Nakagawa 1970

机译：甲基2,3-α-苄基-3-硝基-β-D-丙醇苷和Somec2-支链衍生物的制备4,6-O-苄基 - 2,3 - 德奈氧基-3-硝基-β-D-葡糖吡喃糖苷
8. Composite Materials with Improved Properties in Compression. Appendix 1.Cyclopropanation of Poly(1-Methyl-1-phenyl-1-sila-cis-pent-3-ene). Synthesis and Characterization of Poly(1-Methyl-3,4-methylene-1-phenyl-1-sila-cis-pent-3-ene) [R] . Liao, X., Lee, H. S., Weber, W. P. 1990

机译：压缩性能改善的复合材料。附录1.聚（1-甲基-1-苯基-1-硅杂 - 顺式 - 戊-3-烯）的环丙烷化。聚（1-甲基-3,4-亚甲基-1-苯基-1-硅杂 - 顺式 - 戊-3-烯）的合成与表征

IMPROVED SYNTHESIS OF METHYL 4,6-O-BENZYLIDENE-3-CYANO-2,3-DIDEOXY-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE AND METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-C-FORMYL-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSI DE

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