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Dynamic rheology of rice starch-galactomannan mixtures in the aging process

机译:大米淀粉-半乳甘露聚糖混合物在老化过程中的动态流变学

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摘要

The effect of galactomananns (guar gum and locust bean gum) at different concentrations (0, 0.2, 0.4, 0.6 and 0.8%, w/w) on the dynamic rheological properties of aqueous rice starch dispersions (5%, w/w) was investigated by small-deformation oscillatory measurements during aging. Magnitudes of storage (G') and loss (G") moduli measured at 4 degrees C before aging increased with the increase in gum concentration in the range of 0.2-0.8%. G' and G" values of rice starch-locust bean gum (LBG) mixtures, in general, were higher than those of rice starch-guar gum mixtures. G' values of rice starchguar gum mixtures as a function of aging time (10 h) at 4 degrees C increased rapidly at initial stage and then reached a plateau region at long aging times. However, G' values of rice starch-LBG mixtures increased steadily without showing a plateau region. Increasing the guar gum concentration resulted in an increase in plateau values. The rate constant (K) for structure development during aging was described by first-order kinetics. K values in rice starch-guar gum mixtures increased with the increase in guar gum concentration. G' values of rice starch-galactomannan mixtures after aging were greater than those before aging.
机译:不同浓度(0、0.2、0.4、0.6和0.8%,w / w)的半乳聚糖(瓜耳胶和刺槐豆胶)对稻米淀粉水分散体(5%,w / w)的动态流变特性的影响为通过老化过程中的小变形振荡测量进行了研究。老化前在4摄氏度下测得的储能(G')和模量(G“)随胶浓度在0.2-0.8%范围内的增加而增加。大米淀粉-刺槐豆胶的G'和G”值(LBG)混合物通常要比大米淀粉-瓜尔胶混合物高。大米淀粉瓜尔胶混合物的G'值在4摄氏度时随老化时间(10小时)的变化在初始阶段迅速增加,然后在较长的老化时间达到平稳区域。但是,大米淀粉-LBG混合物的G'值稳定增加,而没有出现平稳区域。瓜尔豆胶浓度的增加导致平台值的增加。通过一阶动力学描述了老化过程中结构发展的速率常数(K)。大米淀粉-瓜尔豆胶混合物中的K值随瓜尔豆胶浓度的增加而增加。老化后的大米淀粉-半乳甘露聚糖混合物的G'值大于老化前。

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