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首页> 外文期刊>Ceramic Engineering and Science Proceedings >CELLULAR CERAMICS MADE OF SILICON CARBIDE CERAMICS FOR BURNER TECHNOLOGY
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CELLULAR CERAMICS MADE OF SILICON CARBIDE CERAMICS FOR BURNER TECHNOLOGY

机译:燃烧器技术用碳化硅陶瓷制成的蜂窝陶瓷

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Cellular ceramics have been of increased interest for applications in burner technology. High power density of the burners up to some MWm{sup}(-2) raises the load on the materials regarding thermal shock and temperature. Silicon carbide (SiC) ceramics is favoured for such applications, because it combines low CTE, high thermal conductivity and emissivity as well as good stability at high temperatures. Nevertheless cellular ceramics have a high inner surface and lower strength compared to the bulk. This results in problems with crack resistance and long time oxidation stability. Manufacturing of cellular ceramic components needs special efforts to find a good compromise between shaping method and material properties. To tackle these problems the following methods were used to enhance stability of burner components: (1) thermomechanical simulation, (2) model experiments to calculate long time oxidation resistance, (3) optimisation of materials, cellular structure and manufacturing technology and (4) experiments in laboratory burner equipment for validation Open cell foams made of siliconized SiC provide highest strength but limited operating temperature because of the melting of the free silicon. Burners with intermediate heat load can use such foams for a very long time, because of a stable passivation layer. Sintered or recrystallized SiC foams resist higher temperatures than SiSiC but exhibit limited long time oxidation stability only, if they contain open microporosity. Special designed IR-emitter plates with aligned cells possess high durability against thermals shock. A special developed sintered SiC has been used showing good oxidations resistance which allows the prediction of a 3-5 years lifetime at least.
机译:蜂窝陶瓷对于燃烧器技术中的应用引起了越来越多的兴趣。高达MWm {sup}(-2)的燃烧器的高功率密度增加了材料在热冲击和温度方面的负担。碳化硅(SiC)陶瓷因其低CTE,高导热率和发射率以及高温下的良好稳定性而受到青睐。但是,与整体相比,多孔陶瓷具有较高的内表面和较低的强度。这导致了抗裂性和长时间氧化稳定性的问题。多孔陶瓷部件的制造需要特殊的努力,以在成型方法和材料性能之间找到良好的折衷。为了解决这些问题,使用以下方法来增强燃烧器组件的稳定性:(1)热机械模拟;(2)模型实验以计算长时间的抗氧化性;(3)材料,单元结构和制造技术的优化;(4)实验室燃烧器设备中的实验进行验证由硅化SiC制成的开孔泡沫具有最高的强度,但由于游离硅的熔化而使工作温度受到限制。具有中等热负荷的燃烧器由于具有稳定的钝化层,因此可以长时间使用这种泡沫。烧结或重结晶的SiC泡沫具有比SiSiC更高的耐温性,但如果它们具有开放的微孔性,则仅表现出有限的长时间氧化稳定性。特殊设计的带有对准单元的红外发射板具有很高的抗热冲击耐久性。已使用一种特殊开发的烧结SiC,它具有良好的抗氧化性,因此至少可以预测3-5年的使用寿命。

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