首页> 外文期刊>Solid state sciences >Electrical and optical properties of inorganic complexes C_(36)H_(76)N_2O_9ClNa and C_(14)H_(12)N_2O_4TeBr_2
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Electrical and optical properties of inorganic complexes C_(36)H_(76)N_2O_9ClNa and C_(14)H_(12)N_2O_4TeBr_2

机译:无机配合物C_(36)H_(76)N_2O_9ClNa和C_(14)H_(12)N_2O_4TeBr_2的电和光学性质

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摘要

The electrical properties of some inorganic samples were studied as functions of temperature and the results were analyzed. These samples activation energies were calculated from the electrical conductivity measurements. Also, a detailed study of optical absorption is presented. The optical absorption spectra are measured in the UV + invisible wavelength range 200-1100 nm. The absorption coefficient and value optical energy gaps were determined from the absorption spectra. The complex C_(36)H_(76)N_2O_9ClNa is characterized by direct optical absorption with an optical edge at 4.49 eV. However, the complex C_(14)H_(12)N_2O_4TeBr_2 is characterized by indirect optical absorption with an optical edge at 1.45 eV, and a nearby direct one at hv = 1.80 eV.
机译:研究了一些无机样品的电性能随温度的变化,并对结果进行了分析。从电导率测量值计算出这些样品的活化能。另外,提出了光吸收的详细研究。在200 + 1100 nm的UV +不可见波长范围内测量光吸收光谱。由吸收光谱确定吸收系数和值光能隙。络合物C_(36)H_(76)N_2O_9ClNa的特征在于直接光吸收,其光学边缘为4.49 eV。但是,复合物C_(14)H_(12)N_2O_4TeBr_2的特征是间接光吸收,其光学边缘为1.45 eV,附近为hv = 1.80 eV。

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