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Carbon-metal (Ni or Ti) nanocomposite thin films for functional applications

机译:用于功能应用的碳金属(Ni或Ti)纳米复合薄膜

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摘要

A comparison between structure and mechanical properties of dc sputtered C-Ni and C-Ti nanocomposite thin films has been made in the growth temperature range of 25-800 deg C. C-Ni films undergo morphological and phase change at 400 deg C deposition temperature, while the C-Ti films possess the same phase state and morphological character in the whole range of deposition temperatures. Despite the structural differences the dependence of hardness (H) and elastic modulus (E) on the deposition temperature shows very similar behavior. The same character of the hardness and modulus curves is mostly influenced by the structure and the morphology of the carbon matrix. The difference in absolute value between the H and E curves of C-Ni and C-Ti could be related to the C-metal bonds, chemical stability and mechanical properties of the corresponding carbide phase.
机译:在25-800摄氏度的生长温度范围内,对直流溅射C-Ni和C-Ti纳米复合薄膜的结构和力学性能进行了比较。C-Ni薄膜在400摄氏度的沉积温度下会发生形变和相变,而C-Ti膜在整个沉积温度范围内具有相同的相态和形态特征。尽管结构上存在差异,但硬度(H)和弹性模量(E)对沉积温度的依赖性表现出非常相似的行为。硬度和模量曲线的相同特征主要受碳基质的结构和形态影响。 C-Ni和C-Ti的H和E曲线的绝对值差异可能与相应碳化物相的C-金属键,化学稳定性和力学性能有关。

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