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Efficient Red Electroluminescent Devices Based on Inter-Ligand Energy Transfer of Heteroleptic Tris-Cyclometaiated iridium Complexes

机译:基于配体间Tris-环甲酰化铱配合物的配体间能量转移的红色电致发光器件

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摘要

Red heteroleptic tris-cyclometalated iridium complex, Ir(ppy){sub}2(dpq-3-F), have been characterized. When Ir(ppy){sub}2(dpq-3-F) is placed in the excited state, the excitation energy is quickly intramolecular transferred from two ppy to one luminescent dpq-3-F. Thus, Ir(ppy){sub}2(dpq-3-F) shows emission at 620nm from dpq-3-F. The device with Ir(ppy){sub}2(dpq-3-F) showed superior electrical characteristics by decreasing self-quenching.
机译:表征了红色杂配的三环金属铱化合物Ir(ppy){sub} 2(dpq-3-F)。当Ir(ppy){sub} 2(dpq-3-F)处于激发态时,激发能迅速从分子内从2 ppy转移到一个发光dpq-3-F。因此,Ir(ppy){sub} 2(dpq-3-F)显示出来自dpq-3-F的620nm处的发射。具有Ir(ppy){sub} 2(dpq-3-F)的器件通过减少自淬火而显示出优异的电气特性。

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