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Adsorption of nickel(II) from aqueous soltuoin onto activated carbon prepared from coirpith

机译:钴皮中制备的活性炭对水溶液中镍(II)的吸附

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Activated carbon has been prepared from coirpith by chemical activation and characterized. Carbonised coirpith is able to adsorb Ni(II) from aqueous solution. It was noted that a devreasing in the carbon concentration with constant Ni concentration, or an increase in the Ni concentration with constant carbon concentration resulted in a higher nickel uptake per unit weight of carbon. The Langmuir and Freudlich models for dynamics of metal ion uptake porposed in this work fit the experimental data reasonably well. The adsorption (Q_0) calculated from Langmuir isotherm was 62.5 mg Ni(II) g~(-1) at initial pH of 5.0 at 30 deg C for the particle size 250-500 #mu#m. The adsorption of Ni increased with pH from 2 to 7 and remained constant upto 10. The recovery of Ni(II) after adsorption can be carried out by treatment of the Ni loaded carbon with HCl. Desoption studies confirms adsorption is ion exhcange. As coirpith is discarded as waste material from coir processing industries, the carbon is expected to be economical product for metal ion remediation from water and wastewater.
机译:活性炭已通过化学活化从椰皮中制备并表征。碳化的椰菜皮能够从水溶液中吸附Ni(II)。注意到在恒定的Ni浓度下碳浓度的增加,或者在恒定的碳浓度下Ni浓度的增加导致每单位重量碳更高的镍吸收。 Langmuir和Freudlich模型的金属离子吸收动力学可以很好地拟合实验数据。由Langmuir等温线计算的吸附(Q_0)在30℃下初始pH为5.0时对于250-500#μm的粒径为62.5mg Ni(II)g〜(-1)。 Ni的吸附随pH从2增加到7而增加,并一直保持恒定,直到10。吸附后的Ni(II)回收可通过用HCl处理负载Ni的碳来进行。解吸研究证实吸附是离子释放。由于椰皮被作为椰壳加工业的废料而丢弃,因此碳有望成为从水和废水中修复金属离子的经济产品。

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