Preparation of Al_2O_3-ZrO_2-Y_2O_3 Composite Coatings by a Modified Sol-Gel Technique for Thermal Barrier Application

摘要

Spatial-network Al_2O_3-ZrO_2-Y_2O_3 composite coatings were prepared by a modified sol-gel technique, so-called thermal pressure and filtration of sol-gel paint. The composite coatings were derived from a composite paint of yttria partially stabilized zirconia (YSZ) particles, Al_2O_3 particles and Al_2O_3-Y_2O_3 sol. Their microstructure showed that YSZ particles were covered with spatial-network Al_2O_3-Y_2O_3 blanket. Cyclic oxidation at 1,050 °C in air for 200 h demonstrates that the oxygen diffusion rate in the coatings could be effectively inhibited. Meanwhile, suitable coefficients of thermal expansion (CTE) gave the composite coatings better spallation resistance than that of Al_2O_3-Y_2O_3 or ZrO_2-Y_2O_3 coat-ings. The positive results of cyclic oxidation indicated that the composite coating can be used as an interlayer between the bond coat and the top ceramic layer in traditional TBCs. Not only the depletion rate of aluminum-rich phase in MCrAlY alloy could be slowed down by spatial-network Al_2O_3-Y_2O_3, but also different thermal expansion between thermally grown oxides layer and top layer could berelieved by suitable CTE. In this paper, the mechanisms of the inhibition of oxygen diffusion and thermal match between ceramic coating and alloy are also discussed.