Reactions of (Hydroxo)aluminium(III)tetra(4-chloro)phthalocyanine in Sulfuric Acid

E. E. Suslova; T. N. Sokolova; T. N. Lomova; S. V. Zaitseva; S. A. Zdanovich

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Reactions of (Hydroxo)aluminium(III)tetra(4-chloro)phthalocyanine in Sulfuric Acid

机译：（羟基）铝（III）四（4-氯）酞菁在硫酸中的反应

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Spectrophotometric and quantum-chemical data showed that (hydroxo)aluminium(III)tetra(4-chloro)phthalocyanine forms one p9rotonated form (trans-dication) in aqueous concentrated H_2SO_4. The kinetics of the protonated complex dissociation across the Al-N bonds is studied. The effect of the halogen substitution in the aluminium phthalocyanine macrocycle on its basicity and stability is discussed.

机译：分光光度法和量子化学数据表明，（羟基）铝（III）四（4-氯）酞菁在浓H_2SO_4水溶液中形成一种对硝基苯磺酸化（trans-dication）形式。研究了穿过Al-N键的质子化复合物解离的动力学。讨论了铝酞菁大环中卤素取代对其碱性和稳定性的影响。

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《Russian Journal of Coordination Chemistry》 |2003年第8期|共5页
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E. E. Suslova; T. N. Sokolova; T. N. Lomova; S. V. Zaitseva; S. A. Zdanovich;
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1. Reactions of (Hydroxo)aluminium(III)tetra(4-chloro)phthalocyanine in Sulfuric Acid [J] . E. E. Suslova, T. N. Sokolova, T. N. Lomova, Russian Journal of Coordination Chemistry . 2003,第8期

机译：（羟基）铝（III）四（4-氯）酞菁在硫酸中的反应
2. Reactions of Nitro and Halonitro Derivatives of Aluminum(III) and Copper(II) Phthalocyanines with Concentrated Sulfuric Acid [J] . T. N. Sokolova, T. N. Lomova, E. E. Suslova, Russian Journal of General Chemistry . 2002,第6期

机译：铝（III）和铜（II）酞菁的硝基和卤代硝基衍生物与浓硫酸的反应
3. A kinetic fluorometric method for the determination of nucleic acids using a ternary equilibrium system of nucleic acids-iron (III) tetracarboxy phthalocyanine-poly-lysine coupled with the oxidation reaction between hydrogen peroxide and DL-tyrosine [J] . Chang-Qing Zhu, Shu-Juan Zhuo, Jin-Long Chen, Analytica chimica acta . 2004,第2期

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4. The oxygen reduction reaction catalyzed by carbon-supported copper phthalocyanine tetrasulfonic acid (CuPcTSA/C) by high temperature treatment [C] . Xin Qing, Jingjing Shi, Pan Xu, Polymer Electrolyte Fuel Cells Symposium;Meeting of The Electrochemical Society . 2013

机译：碳载铜酞菁四磺酸（CuPcTSA / C）高温处理催化的氧还原反应
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6. Susceptibility of In Vitro Melanoma Skin Cancer to Photoactivated Hypericin versus Aluminium(III) Phthalocyanine Chloride Tetrasulphonate [O] . I. M. Ndhundhuma, H. Abrahamse 2006

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7. Equilibrium and Structural Studies of Silicon(IV) and Aluminium(III) in Aqueous Solution. 4. A Potentiometric Study of Polynuclear Aluminium(III) Hydroxo Complexes with Gallic Acid in Hydrolyzed Aluminium(III) Solutions. [O] . Lars-Olof Öhman, Staffan Sjöberg, Per Jennische, 1982

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Reactions of (Hydroxo)aluminium(III)tetra(4-chloro)phthalocyanine in Sulfuric Acid

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