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SILAR coated Bi2S3 nanoparticles on vertically aligned ZnO nanorods: Synthesis and characterizations

机译:垂直排列的ZnO纳米棒上SILAR涂层的Bi2S3纳米颗粒:合成与表征

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摘要

Simple and inexpensive wet chemical route, namely successive ionic layer adsorption and reaction (SILAR) is demonstrated to coat the inorganic semiconducting Bi2S3 nanoparticles (NPs) at room temperature on chemical bath deposited vertically aligned ZnO nanorods (NRs). The films were characterized by X-ray diffraction (XRD), UV-vis spectroscopy, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray analysis (EDX), Raman spectroscopy and surface profiler in order to confirm the crystal structure, optical properties, surface morphology, elemental compositions and film thickness. Finally, the solar cell device was formed by using Bi2S3 coated ZnO NRs as photoanode, liquid electrolyte as hole conducting media and platinum (Pt) as a back contact. The power conversion efficiency (eta) of 0.025% under illumination of simulated sunlight (AM 1.5 G, 100 mW/cm(2)) was observed. (C) 2015 Published by Elsevier Ltd and Techna Group S.r.l.
机译:事实证明,简单且廉价的湿化学路线,即连续的离子层吸附和反应(SILAR),可以在室温下在垂直沉积的ZnO纳米棒(NRs)的化学浴上涂覆无机半导体Bi2S3纳米颗粒(NPs)。通过X射线衍射(XRD),紫外可见光谱,场发射扫描电子显微镜(FE-SEM),能量色散X射线分析(EDX),拉曼光谱和表面轮廓仪对薄膜进行表征,以确认晶体结构,光学性质,表面形态,元素组成和薄膜厚度。最后,太阳能电池装置是通过使用Bi2S3涂层的ZnO NRs作为光阳极,液体电解质作为空穴传导介质以及铂(Pt)作为背接触而形成的。观察到模拟太阳光(AM 1.5 G,100 mW / cm(2))照射下的功率转换效率(η)为0.025%。 (C)2015由Elsevier Ltd和Techna Group S.r.l.

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