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The relationship between oxygen consumption rate and temperature during coal spontaneous combustion

机译:煤自燃过程中耗氧率与温度的关系

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摘要

Spontaneous combustion is a major natural disaster in coal production. In the process of exploring coal self-ignition, a series of hypotheses have been put forward, most scholars agree that the current coal-oxygen compound theory. Oxygen consumption rate reflects the status of coal spontaneous combustion, and it is also one of the parameters necessary for numerical simulation of coal spontaneous combustion. In this paper, a coal heating and oxidation experiment was designed, Experimental device consists of heating and oxidation furnace, gas chromatograph, temperature control and data acquisition systems and other equipment components. Three coal samples whose weight each is 5 g were selected for the study. By experiment, oxygen concentration at the inlet and outlet of temperature oxidation furnace was measured. Oxygen consumption rate is calculated in the heating process of coal according to air flow. In the Cartesian coordinate system, the temperature as abscissa and the oxygen consumption rate for the longitudinal coordinates, drawing the relationship between oxygen consumption rate and temperature plot. And then regression analysis was used to analyze the relationship between oxygen consumption rate and coal temperature during the heating and oxidation process of coal. The results show that the oxygen consumption rate and temperature of coal were linear relationships both before and after the critical temperature when the coal temperature is less than 180℃. Before the critical temperature oxygen consumption rate is low, however it increases rapidly when coal temperature reaches a critical temperature. The result is important for the prevention and treatment of spontaneous combustion of coal.
机译:自燃是煤炭生产中的主要自然灾害。在探索煤自燃过程中,提出了一系列假说,多数学者认为目前的煤-氧复合理论。耗氧率反映了煤自燃的状态,也是煤自燃数值模拟的必要参数之一。本文设计了一种煤加热氧化实验,实验装置由加热氧化炉,气相色谱仪,温度控制及数据采集系统等设备组成。选择了三个煤样品,每个样品的重量为5 g。通过实验,测量了温度氧化炉入口和出口的氧气浓度。耗氧率是在煤加热过程中根据空气流量计算得出的。在笛卡尔坐标系中,温度为横坐标,耗氧率为纵坐标,绘制了耗氧率与温度图之间的关系。然后通过回归分析来分析煤加热和氧化过程中耗氧率与煤温之间的关系。结果表明,当煤温低于180℃时,临界温度前后煤的耗氧率与温度呈线性关系。在临界温度之前,氧气消耗率很低,但是当煤温度达到临界温度时,氧气消耗率会迅速增加。该结果对于预防和处理煤的自燃具有重要意义。

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