Preparation and mechanical characterization of dense and porous zirconia produced by gel casting with gelatin as a gelling agent

摘要

A modified gel casting procedure based on a natural gelatin for food industry and commercial polyethylene spheres as pore formers was successfully exploited to produce dense and porous ceramic bodies made of yttria stabilized tetragonal zirconia polycrystal (Y-TZP). Vickers and Knoop microhardness, elastic modulus and fracture toughness measurements on dense samples obtained by experimental investigation closely matched results found in the literature for similar materials. However, after a careful analysis of obtained results, no indentation size effect and a lower scattering of experimental data from low load indentations were observed, in comparison with literature. Mechanical testing of porous samples (with reproducible values of porosity of about 40 percent) evidenced a high scattering of compressive strength values, suggesting that the uneven distribution of cavities in the material or the presence of defects from the agglomeration of pore forming agents could have a more direct influence on the mechanical properties of such materials than the absolute value of porosity.