Synthesis, structure, and reductive elimination reactions of the first (sigma-aryl)palladium complex stabilized by IPr N-heterocyclic carbene

Marshall WJ.; Grushin VV.

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Synthesis, structure, and reductive elimination reactions of the first (sigma-aryl)palladium complex stabilized by IPr N-heterocyclic carbene

机译：IPr N-杂环卡宾稳定的第一个（σ-芳基）钯配合物的合成，结构和还原消除反应

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The first (s-aryl)palladium complex stabilized with one IPr N-heterocyclic carbene and one PPh3 ligand has been synthesized via a novel method, structurally characterized, and found to undergo remarkably facile C-C reductive elimination of the 2-phenylimida-zolium cation via phosphine predissociation. [References: 27]

机译：用一种新的方法合成了用一个IPr N-杂环卡宾和一个PPh3配体稳定的第一个（s-芳基）钯配合物，结构表征了该化合物，并发现该化合物可通过以下方法非常容易地CC还原消除2-苯基亚咪唑鎓阳离子膦预离解。 [参考：27]

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《Organometallics》 |2003年第8期|共3页
作者
Marshall WJ.; Grushin VV.;
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正文语种 eng
中图分类有机化学;
关键词
Palladium/imidazolium salt systems; Coupling reactions; Aryl chlorides; Palladium(ii) complexes; Oxidative addition; Stable carbenes; Amination; Halides; Catalysis; Exchange;

机译：钯/咪唑鎓盐体系;偶联反应;芳基氯;钯（ii）配合物;氧化加成;稳定的卡宾;胺化;卤化物;催化;交换;

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1. Synthesis, structure, and reductive elimination reactions of the first (sigma-aryl)palladium complex stabilized by IPr N-heterocyclic carbene [J] . Marshall WJ., Grushin VV. Organometallics . 2003,第8期

机译：IPr N-杂环卡宾稳定的第一个（σ-芳基）钯配合物的合成，结构和还原消除反应
2. Synthesis and Reaction of MnII Iodides Bearing the -Diketiminate Ligand: the First Divalent Manganese N-Heterocyclic Carbene Complexes [{HC(CMeNAr)_2}MnI{C[N(iPr)CMe]_2}] and [{HC(CMeNAr)_2}MnNHAr{C[N(iPr)CMe]_2}] (Ar = 2,6-iPr2C_6H_3) [J] . Jiangfang Chai, Hongping Zhu, Kerstin Most, European journal of inorganic chemistry . 2003,第24期

机译：带有-二甲醚配体的MnII碘化物的合成和反应：第一个二价锰N-杂环碳原子络合物[{HC（CMeNAr）_2} MnI {C [N（iPr）CMe] _2}]和[{HC（CMeNAr）_2 } MnNHAr {C [N（iPr）CMe] _2}]（Ar = 2,6-iPr2C_6H_3）
3. Synthesis, Characterization, Crystal Structures, and Catalytic C-C Coupling and Hydrosilylation Reactions of Palladium(II) Complexes Derived from CNC Pincer-Type N-Heterocyclic Carbenes [J] . Haque Rosenani A., Asekunowo Patrick O., Budagumpi Srinivasa, European journal of inorganic chemistry . 2015,第19期

机译：CNC钳形N杂环卡宾衍生的钯（II）配合物的合成，表征，晶体结构以及催化的C-C偶联和氢化硅烷化反应
4. Ruthenium–Indenylidene Complexes Bearing Saturated N-Heterocyclic Carbenes: Synthesis and Application in Ring-Closing Metathesis Reactions [C] . Stijn Monsaert, Els De Canck, Renata Drozdzak, NATO Advanced Study Institute on Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology . 2010

机译：含饱和N-杂环的钌 - 茚基三苯基复合物：在闭环复分解反应中的合成和应用
5. 1. Axially-chiral 7-membered N-heterocyclic carbenes: Synthesis and application to palladium-catalyzed intramolecular aerobic oxidation of olefins 2. Development of palladium-catalyzed aerobic oxidative olefin amination reactions [D] . Scarborough, Christopher C. 2008

机译：1.轴向手性7元N-杂环卡宾：烯烃的钯催化分子内需氧氧化的合成及应用2.钯催化需氧氧化烯烃胺化反应的发展
6. Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions [O] . Ziya Sahin, Senem Akkoς, İlhan Özer İlhan, 2017

机译：N-杂环碳钯钯：苯并咪唑鎓盐的合成及其在碳-碳键形成反应中的催化活性
7. Dinuclear Gold(I) Complexes Bearing Alkyl-Bridged Bis(N-heterocyclic carbene) Ligands as Catalysts for Carboxylative Cyclization of Propargylamine: Synthesis, Structure, and Kinetic and Mechanistic Comparison to the Mononuclear Complex Au(IPr)Cl [O] . -1

机译：二核金（I）复合物轴承烷基桥接双（N-杂环碳切菜）配体作为丙基胺的羧基环化的催化剂：合成，结构和动力学和机械和机械与单核络合物Au（IPR）Cl的催化剂比较
8. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex. [R] . Sara, V., Kornenko, N., Margarit, C. G., 2013

机译：可见光光催化氧化催化：用镍N-杂环卡宾 - 异喹啉配合物选择性还原二氧化碳为一氧化碳。

Synthesis, structure, and reductive elimination reactions of the first (sigma-aryl)palladium complex stabilized by IPr N-heterocyclic carbene

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