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首页> 外文期刊>Oriental Journal of Chemistry: An International Research Journal of Pure & Applied Chemistry >Synthesis and structural studies of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes of 2-methyl- benzoxazole-5-carboxylic acid (2-hydroxy-benzylidene)-hydrazide [MBCHBH]
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Synthesis and structural studies of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes of 2-methyl- benzoxazole-5-carboxylic acid (2-hydroxy-benzylidene)-hydrazide [MBCHBH]

机译:Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II),Zn(II),Cd(II)和Hg(II)配合物的合成和结构研究2-甲基-苯并恶唑-5-羧酸(2-羟基-亚苄基)酰肼[MBCHBH]

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摘要

The complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with 2-methyl-benzoxazole-5-carboxylic acid (2-hydroxy-benzylidene)-hydrazide [MBCHBH] have been synthesized and structurally characterized on the basis of analytical, conductance, thermal, magnetic and infrared, electronic and esr spectral data. The ligand MBCHBH behaves as a mononegative, tridentate one coordinating through phenolic oxygen, amid group oxygen and azomethine nitrogen.
机译:Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II),Zn(II),Cd(II)和Hg(II)与2-根据分析,电导,热,磁和红外,电子和esr光谱数据,合成了甲基-苯并恶唑-5-羧酸(2-羟基-亚苄基)-酰肼[MBCHBH],并对其结构进行了表征。配体MBCHBH表现为单负,三齿配位体,通过酚氧,氧基和偶氮甲碱氮进行配位。

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