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Synthesis, optical and thermal studies on novel semi organic nonlinear optical Urea Zinc Acetate crystals by solution growth technique for the applications of optoelectronic devices

机译:溶液生长技术对新型半有机非​​线性光学光学醋酸脲锌晶体的合成,光学和热学研究

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摘要

Urea Zinc Acetate (UZA), a novel semi organic nonlinear optical crystal having dimensions 30 × 28 × 10 mm~3 has been synthesized using slow evaporation technique. The lattice parameters for the grown crystals were determined using single crystal XRD. The presence of functional groups for the grown crystals was confirmed using Fourier Transform Infrared (FT-IR) spectroscopy. The optical absorption studies show that the material has wide optical transparency in the entire visible region. The thermal stability of the crystal was determined from thermo gravimetric and differential thermal analysis curve. The second harmonic generation was confirmed by Kurtz powder method and it is found to be 3 times than that of KDP crystal.
机译:采用慢蒸发技术合成了尺寸为30×28×10 mm〜3的新型半有机非​​线性光学晶体尿素醋酸锌(UZA)。使用单晶XRD确定生长晶体的晶格参数。使用傅立叶变换红外(FT-IR)光谱确认了生长晶体的官能团的存在。光学吸收研究表明,该材料在整个可见光区域具有较宽的光学透明性。晶体的热稳定性由热重和差示热分析曲线确定。通过Kurtz粉末法确认了二次谐波的产生,发现其为KDP晶体的3倍。

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