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首页> 外文期刊>Russian Journal of Inorganic Chemistry >Synthesis, IR Spectra, and Solid-State Luminesc nee of Triphenylguanidinium Salts with the Anions B_(10)H_(10)~(2-), B_(12)H_(12)~2-, B_9C_2H_(12)~2-, [Co(C_2B_9H_(11))_2]~-, and [Ni(C_2B_9H_(11))_2]~-
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Synthesis, IR Spectra, and Solid-State Luminesc nee of Triphenylguanidinium Salts with the Anions B_(10)H_(10)~(2-), B_(12)H_(12)~2-, B_9C_2H_(12)~2-, [Co(C_2B_9H_(11))_2]~-, and [Ni(C_2B_9H_(11))_2]~-

机译:阴离子B_(10)H_(10)〜(2-),B_(12)H_(12)〜2-,B_9C_2H_(12)〜2-的三苯基胍盐的合成,红外光谱和固态发光,[Co(C_2B_9H_(11))_ 2]〜-和[Ni(C_2B_9H_(11))_ 2]〜-

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摘要

Triphenylguanidinium Ph_3GH~+ salts with the anions B_(10)H_(10)~(2-), B_(12)H_(12)~(2-), B_9C_2H_(12)~-, [Co(C_2B_9H_(11))_2]~-, and [Ni(C_2B_9H_(11))_2]~ -were synthesized and described by DTA, IR spectroscopy, and solid-state luminescence. By IR spectroscopy, it was shown that intermolecular interactions involving the NH groups of the cation are enhanced in the sequence [Co(C_2B_9H_(11))_2]~-approx [Ni(C_2B_9H_(11))_2]~-
机译:三苯基胍Ph_3GH〜+与阴离子B_(10)H_(10)〜(2-),B_(12)H_(12)〜(2-),B_9C_2H_(12)〜-,[Co(C_2B_9H_(11))形成的盐)_2]〜-和[Ni(C_2B_9H_(11))_ 2]〜-通过DTA,IR光谱和固态发光合成和描述。通过IR光谱,表明涉及阳离子的NH基团的分子间相互作用以[Co(C_2B_9H_(11))_ 2]〜-约[Ni(C_2B_9H_(11))_ 2]〜-

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