Synthesis and Molecular Structure of Cyclopentadienyl(nitrosyl)(carbonyl) Thiolate CpMn(CO)(NO)Sn(SPh)_3 with a Manganese-Tin Bond

A. A. Pasynskii; A. I. Blokhin; S. S. Shapovalov

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Synthesis and Molecular Structure of Cyclopentadienyl(nitrosyl)(carbonyl) Thiolate CpMn(CO)(NO)Sn(SPh)_3 with a Manganese-Tin Bond

机译：带有锰锡键的环戊二烯基（亚硝酰基）（羰基）硫醇盐CpMn（CO）（NO）Sn（SPh）_3的合成和分子结构

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The reaction of CpMn(CO)_2(NO)~+Cl~- with tin dichloride gave a new ionic complex, CpMn(CO)_2(NO)~+SnCl_3~-, which was treated with an excess of sodium thiophenoxide. The resulting cyclopen-tadienyl nitrosyl carbonyl thiolate complex CpMn(CO)(NO)Sn(SPh)_3 containing a Sn(SPh)_3 ligand linked to manganese by a shortened Mn-Sn bond (2.533(2) A) was structurally characterized.

机译：CpMn（CO）_2（NO）〜+ Cl〜-与二氯化锡的反应生成了新的离子络合物CpMn（CO）_2（NO）〜+ SnCl_3〜-，并用过量的噻吩钠处理。在结构上表征了所得到的环戊二烯基亚硝酰基羰基硫醇盐配合物CpMn（CO）（NO）Sn（SPh）_3，该Sp（SPh）_3配体通过缩短的Mn-Sn键与锰连接（2.533（2）A）。

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《Russian Journal of Inorganic Chemistry》 |2007年第6期|共4页
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A. A. Pasynskii; A. I. Blokhin; S. S. Shapovalov;
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1. Synthesis and Molecular Structure of Cyclopentadienyl(nitrosyl)(carbonyl) Thiolate CpMn(CO)(NO)Sn(SPh)_3 with a Manganese-Tin Bond [J] . A. A. Pasynskii, A. I. Blokhin, S. S. Shapovalov Russian Journal of Inorganic Chemistry . 2007,第6期

机译：带有锰锡键的环戊二烯基（亚硝酰基）（羰基）硫醇盐CpMn（CO）（NO）Sn（SPh）_3的合成和分子结构
2. Synthesis, Molecular Structures, and Properties of the Manganese Chalcogenide Complexes CpMn(CO)_2SC(O)Ph, [CpMn(CO)_2]_2(mu-Se_2), CpMn(CO)_2SMe_2, [CpMn(CO)_2]2(mu-SMe_2), and [CpMn(CO)_2]_2(mu-SeMe_2) [J] . A.A. Pasynskii, V.N. Grigorev, Yu. V. Torubaev Russian Journal of Inorganic Chemistry . 2002,第12期

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Synthesis and Molecular Structure of Cyclopentadienyl(nitrosyl)(carbonyl) Thiolate CpMn(CO)(NO)Sn(SPh)_3 with a Manganese-Tin Bond

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