Complexes of the 14th Group Elements with Tridentate Redox-Active Ligand

摘要

New methods of synthesis of the 14th group metal (Si, Sn, Pb) complexes containing a redox-active ligand, 3,5-di-tert-butyl-1,2-quinone-1-(2-hydroxy-3,5-di-tert-butylphenyl)imine, in various redox states were developed. New compounds were studied by the ESR spectroscopy in solutions. The redox properties of the paramagnetic tin compounds are characterized by the cyclic voltammetry. The solvent and temperature effect on the ESR spectra parameters of paramagnetic complexes of Sn(IV)and Pb(IV) was revealed.