Chiral Molecular Cavities Based on 1,4;3,6-Dianhydro-D-mannite Bis(tetramethylphosphorodiamidite)

摘要

The possibility of forming chiral molecular cavities from an accessible bisphosphorylated derivative of 1,4;3,6-dianhydro-D-mannite and various bisphenols was examined. We have studied previously phosphorylation of 1,4;3,6-dianhydro-D-mannite I, a chiral diol in which the hydroxy groups are closely located in spaace, with amides of trivalent phosphorus acids [1].