Ion-Molecular Reactions of Free Phenyl Cations with Diethylamine in the Gas Phase: Radiochemical Study

摘要

Ion-molecular reactions of free phenyl catoins with diethylamine in the gas phase were studied radiochemically. The reaction practically totally follows the pathway of proton transfer, which occurs in the intermediate complex not only from the incoming cation (C_6H_5~+) but also from the ethyl substituent of the amine. Also, products of the reaction of diethylamine with benzyne (C_6H_4) generated by proton abstraction from the phenyl cation were detected.