Mechanochemical Synthesis of Poly(germanium and tin organosiloxanes)

摘要

The mechanochemical reaction of polyphenylsiloxane with tin and germanium oxides gives rise to soluble tin and germanium phenylsiloxanes.Effect of the nature of the oxide and of the starting reagent ratio on the yield and composition of metal phenylsiloxanes was studied.The reaction products were studied by IR spectroscopy and X-ray phase analysis.