Influence of Aromatic Compounds on Catalytic Oxidation of Alcohols in the System Pd(II) Tetraaqua Complex-Fe(III) Aqua Ion

摘要

We have found previously [1] that aliphatic alcohols C_1-C_3 are catalytically oxidized to the corresponding carbonyl compounds in the system palladi-um(II) tetraaqua complex-iron(III) aqua ion.In the course of oxidation,palladium is reduced to the intermediate oxidation state Pd(I),which precedes formation of a small palladium cluster,an actual catalytic species [1,2].